{"id":"W2577952833","doi":"10.1016/j.electacta.2017.01.089","title":"Study of the Pt (111) | electrolyte interface in the region close to neutral pH solutions by the laser induced temperature jump technique","year":2017,"lang":"en","type":"article","venue":"Electrochimica Acta","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":60,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"Ministerio de Economía y Competitividad; Generalitat Valenciana; Mountain Equipment Co-operative","keywords":"Hydrofluoric acid; Chemistry; Electrolyte; Aqueous solution; Perchlorate; Cyclic voltammetry; Temperature jump; Fluoride; Analytical Chemistry (journal); Inorganic chemistry; Adsorption; Electrode potential; Ion; Electrode; Electrochemistry; Physical chemistry; Chromatography","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008225733,0.0001387741,0.0001811339,0.000168821,0.0002215987,0.0002588054,0.0003859968,0.0004104823,0.002864452],"category_scores_gemma":[0.0002347951,0.0001332792,0.0001160456,0.0001744021,0.0002614066,0.0003118321,0.0002097475,0.000673202,0.0002058017],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001448412,"about_ca_system_score_gemma":0.0001126374,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006194072,"about_ca_topic_score_gemma":0.0005593152,"domain_scores_codex":[0.9999342,0.000004105179,0.000002195323,0.00001710897,0.00002666115,0.00001579782],"domain_scores_gemma":[0.9999135,0.00003662157,0.00001636837,0.000007709885,0.00002001757,0.000005823541],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007084476,0.000009860667,0.0001926583,0.00005295406,0.000003935608,0.00007250231,0.00004568118,0.0000750609,0.9984037,0.0001618498,0.00004928528,0.0008616037],"study_design_scores_gemma":[0.0000164971,0.0001477779,0.005037658,0.000009336549,0.00001526546,0.0001967178,0.0001211854,0.003153209,0.9902136,0.0001271197,0.0009552441,0.000006349897],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943236,0.0005228503,0.00274059,0.0001487994,0.00002388676,0.00001039383,0.0002264379,0.00005997919,0.001943404],"genre_scores_gemma":[0.9975607,0.0002595951,0.001162676,0.00003094436,0.000007622736,0.00001022399,0.0001160673,0.00001382381,0.0008384059],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002864452,"threshold_uncertainty_score":0.00958252,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01771567046626452,"score_gpt":0.2851853129714406,"score_spread":0.2674696425051761,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}