{"id":"W2580537078","doi":"10.1002/chem.201700390","title":"Frustrated Lewis Pair Mediated Csp<sup>3</sup>−H Activation","year":2017,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Frustrated Lewis pair; Chemistry; Hydride; Cleavage (geology); Nitrogen atom; Aryl; Molecule; Stereochemistry; Bond cleavage; Lewis acids and bases; Crystallography; Group (periodic table); Catalysis; Materials science; Organic chemistry; Hydrogen","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008529776,0.000221799,0.0001978445,0.00007491728,0.0002421458,0.000200592,0.0003321654,0.0002247153,0.00364581],"category_scores_gemma":[0.0001007823,0.00007749796,0.0001305158,0.00007495501,0.000304692,0.0002351389,0.0005002555,0.0003679663,0.00040889],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002469287,"about_ca_system_score_gemma":0.0001615161,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003614994,"about_ca_topic_score_gemma":0.0005361604,"domain_scores_codex":[0.9999106,0.00001213847,0.000001899323,0.00001025649,0.0000220073,0.00004304833],"domain_scores_gemma":[0.999965,0.000008686125,0.000009049479,0.000005790943,0.000003265614,0.000008321734],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004081,0.00008250771,0.0004673614,0.0003876642,0.00004264346,0.001069616,0.0002141488,0.003417142,0.958005,0.01714381,0.003248724,0.01551339],"study_design_scores_gemma":[0.0001046168,0.0005827897,0.00116631,0.00001136724,0.00001079426,0.0005403497,0.0000838935,0.01062922,0.9720252,0.002830947,0.01197709,0.00003734127],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9743464,0.0004379583,0.005932584,0.0002866662,0.0000783692,0.00004445822,0.0002003871,0.0001401983,0.01853292],"genre_scores_gemma":[0.9979668,0.00009411003,0.000586995,0.00003485038,0.000007375212,0.0000135391,0.00004786511,0.00000958317,0.001239067],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00364581,"threshold_uncertainty_score":0.01219642,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02056605973955893,"score_gpt":0.233081019287315,"score_spread":0.212514959547756,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}