{"id":"W2583866577","doi":"10.1002/celc.201700059","title":"Probing Excimers of Pt(II) Compounds with Phenyl‐1,2,3‐Triazolyl and Pyridyl‐1,2,4‐Triazolyl Chelate Ligands by Means of Electrochemiluminescence","year":2017,"lang":"en","type":"article","venue":"ChemElectroChem","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Western University","keywords":"Electrochemiluminescence; Phosphorescence; Chemistry; Chemiluminescence; Ammonium persulfate; Photochemistry; Chelation; Persulfate; Methylamine; Excited state; Ligand (biochemistry); Electrochemistry; Fluorescence; Inorganic chemistry; Catalysis; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002643311,0.0003769978,0.000573637,0.0000734878,0.0003022373,0.00003599297,0.0004851218,0.0002727059,0.0000016272],"category_scores_gemma":[0.0001397048,0.0003211451,0.0001448956,0.0001673355,0.0006221546,0.00002109008,0.0002136732,0.0002139788,1.83285e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002592613,"about_ca_system_score_gemma":0.00009701629,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002192366,"about_ca_topic_score_gemma":0.00001704073,"domain_scores_codex":[0.9981786,0.00001405628,0.0004413814,0.0006327946,0.0002632824,0.0004698633],"domain_scores_gemma":[0.9980061,0.00001827262,0.000713364,0.0008584218,0.0002865829,0.0001172674],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003847588,0.0001084786,0.000895477,0.00008559658,0.0002300187,0.000001239333,0.00007089321,3.426962e-7,0.9965002,0.0000282705,0.0005611509,0.001133583],"study_design_scores_gemma":[0.001023616,0.0007736604,0.0001190353,0.0001021036,0.000140641,0.00002688923,0.00006131492,0.00005673414,0.9962969,0.00007268143,0.00093915,0.0003872099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958049,0.001251623,0.001178838,0.0001855631,0.00001722597,0.0002387483,0.00001590195,0.00003990682,0.001267275],"genre_scores_gemma":[0.9957852,0.0009566134,0.002519997,0.00004592378,0.00009184739,0.00001506631,0.0001197034,0.00004231692,0.0004232752],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001341159,"threshold_uncertainty_score":0.9999241,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005691788902254319,"score_gpt":0.2378633457642292,"score_spread":0.2321715568619749,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}