{"id":"W2583866577","doi":"10.1002/celc.201700059","title":"Probing Excimers of Pt(II) Compounds with Phenyl‐1,2,3‐Triazolyl and Pyridyl‐1,2,4‐Triazolyl Chelate Ligands by Means of Electrochemiluminescence","year":2017,"lang":"en","type":"article","venue":"ChemElectroChem","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Western University","keywords":"Electrochemiluminescence; Phosphorescence; Chemistry; Chemiluminescence; Ammonium persulfate; Photochemistry; Chelation; Persulfate; Methylamine; Excited state; Ligand (biochemistry); Electrochemistry; Fluorescence; Inorganic chemistry; Catalysis; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002890476,0.0003436279,0.0001836952,0.0001464494,0.0001097828,0.0003510125,0.0003311343,0.0004713004,0.000587007],"category_scores_gemma":[0.0004769039,0.0001687612,0.0001536251,0.0001344585,0.0003020954,0.0002522495,0.0002658843,0.0005288919,0.0002343895],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004185154,"about_ca_system_score_gemma":0.0001233224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002381747,"about_ca_topic_score_gemma":0.000227618,"domain_scores_codex":[0.9997808,0.00006104745,0.0000147121,0.00005271228,0.00004619477,0.00004447459],"domain_scores_gemma":[0.9997787,0.0000766029,0.00007314138,0.00001873996,0.00002781903,0.00002501485],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002631739,0.000005864916,0.00002932394,0.00001320803,0.000001865103,0.0000141213,0.00001005241,0.00004155116,0.9995479,0.0000342299,0.00001247399,0.0002630746],"study_design_scores_gemma":[0.000004787373,0.00003337187,0.0001622481,9.507684e-7,0.000003068644,0.000025902,0.000003600877,0.0003058182,0.99931,0.000006695814,0.0001425421,9.136251e-7],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889059,0.0006014258,0.00938581,0.0001106349,0.00001427208,0.00001988723,0.00007119071,0.0001079558,0.0007828344],"genre_scores_gemma":[0.9917393,0.0002426759,0.006108797,0.00007386557,0.000007146223,0.00003595796,0.0001180008,0.00002765936,0.001646674],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000587007,"threshold_uncertainty_score":0.003036559,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005691788902254319,"score_gpt":0.2378633457642292,"score_spread":0.2321715568619749,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}