{"id":"W2585035663","doi":"10.1002/anie.201611570","title":"Diazaphospholene Precatalysts for Imine and Conjugate Reductions","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":103,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Conjugate; Imine; Computer science; Combinatorial chemistry; Mathematics; Chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003183812,0.0005038247,0.0003067197,0.0003534158,0.0002420008,0.0002661983,0.0005076249,0.0004270017,0.002498605],"category_scores_gemma":[0.0003681412,0.0002895043,0.0002631558,0.0002742893,0.0003180648,0.0004286197,0.0005880959,0.001308963,0.001253839],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000360013,"about_ca_system_score_gemma":0.0003150955,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002903579,"about_ca_topic_score_gemma":0.0008943131,"domain_scores_codex":[0.9997627,0.00002668647,0.00002328068,0.00004879596,0.00009366622,0.00004483247],"domain_scores_gemma":[0.9999136,0.00002385381,0.00001603438,0.000019512,0.00001582431,0.00001113619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007366539,0.00005577359,0.00007615912,0.0004208556,0.00002059362,0.0004530332,0.0001448831,0.0005177605,0.9697384,0.007125857,0.001050512,0.02032251],"study_design_scores_gemma":[0.00001575887,0.0001454264,0.0001158179,0.000009928913,0.00000870783,0.0003613488,0.00001112473,0.0004262841,0.985216,0.000495681,0.01318175,0.00001212099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.669359,0.02226553,0.2102483,0.00137956,0.001063024,0.001128371,0.00177329,0.002946985,0.08983595],"genre_scores_gemma":[0.9225805,0.009353464,0.05587481,0.0001664128,0.00006698914,0.0002707818,0.000638457,0.0001671393,0.01088138],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002498605,"threshold_uncertainty_score":0.008358657,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01889351511519505,"score_gpt":0.2834127179865943,"score_spread":0.2645192028713992,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}