{"id":"W2585538827","doi":"10.1002/anie.201612549","title":"Optical Distinction between “Slow” and “Fast” Translational Motion in Degenerate Molecular Shuttles","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Rotaxane; Axle; Chemistry; Fluorescence; Molecular machine; Ring (chemistry); Stereochemistry; Photochemistry; Crystallography; Molecule; Nanotechnology; Materials science; Physics; Optics; Organic chemistry; Supramolecular chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000112196,0.0001714207,0.0001465448,0.00004880076,0.0001751294,0.000186546,0.0002481434,0.0001607048,0.0004448768],"category_scores_gemma":[0.0001433009,0.0001925654,0.00007321725,0.00002931102,0.0001400871,0.0003773953,0.00006594373,0.0002056999,0.000008161863],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007114159,"about_ca_system_score_gemma":0.00002253094,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003651592,"about_ca_topic_score_gemma":0.00001406333,"domain_scores_codex":[0.998869,0.000007849696,0.0002590366,0.0003552226,0.0003356277,0.0001732608],"domain_scores_gemma":[0.9994168,0.00005067765,0.0001363778,0.000227021,0.00008759927,0.00008146949],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005847989,0.00008028418,0.02711677,0.00004892988,0.00006324824,0.00003589414,0.00006088891,0.00003819568,0.9619192,0.001550989,0.0001651967,0.00886193],"study_design_scores_gemma":[0.0007757943,0.000006493806,0.02261466,0.00007486294,0.00002634163,0.00002107989,0.00003598893,0.0003924143,0.9706535,0.004175676,0.001027188,0.0001959444],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.946742,0.00007295588,0.01565703,0.0014646,0.0002688129,0.00004971755,0.0001431804,0.00005150322,0.03555023],"genre_scores_gemma":[0.9965969,0.00002524327,0.0004949465,0.00003697563,0.001175005,0.00003419544,0.001378756,0.00001782219,0.0002401864],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04985489,"threshold_uncertainty_score":0.7852589,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01943301483605757,"score_gpt":0.2664169427971857,"score_spread":0.2469839279611281,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}