{"id":"W2587005272","doi":"10.1039/c7cc00516d","title":"Mn(<scp>iv</scp>) and Mn(<scp>v</scp>)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand","year":2017,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Burnaby Hospital; Simon Fraser University","funders":"Labex; Agence Nationale de la Recherche","keywords":"Chemistry; Manganese; Redox; Ligand (biochemistry); Pincer movement; Yield (engineering); Amine gas treating; Radical; Medicinal chemistry; Electron paramagnetic resonance; Pincer ligand; Ion; Chelation; Catalysis; Inorganic chemistry; Organic chemistry; Biochemistry; Nuclear magnetic resonance; Receptor; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":[],"category_scores_codex":[0.0006685904,0.000630937,0.0006892027,0.0001026595,0.001809305,0.0006252177,0.005072331,0.0005604757,0.0001803253],"category_scores_gemma":[0.003758556,0.0005438742,0.0002791467,0.0002825677,0.002195833,0.0004114836,0.002838352,0.00135323,0.0001438534],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001905223,"about_ca_system_score_gemma":0.000181962,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006305172,"about_ca_topic_score_gemma":0.00002145879,"domain_scores_codex":[0.9963338,0.0001132822,0.001074703,0.0008508383,0.0007841699,0.0008431402],"domain_scores_gemma":[0.9894393,0.001934684,0.0008319039,0.006905018,0.0003372865,0.0005517975],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004627337,0.0004053961,0.0005213545,0.00009294239,0.0001935715,0.000005664581,0.0008237999,5.770087e-7,0.9428253,0.001762633,0.05239233,0.0009717996],"study_design_scores_gemma":[0.001155801,0.00001843106,0.0008495977,0.00008862348,0.0001684231,0.00005617327,0.0008728166,0.001049723,0.7535844,0.001058352,0.2409128,0.0001849178],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9440723,0.002510868,0.0004698949,0.005146711,0.0002038027,0.0004999759,0.0008965687,0.0002864634,0.04591342],"genre_scores_gemma":[0.973069,0.001447966,0.00206583,0.0003971092,0.0002442028,0.000268504,0.002859258,0.0001210618,0.01952711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1892409,"threshold_uncertainty_score":0.9997013,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03420441800811717,"score_gpt":0.2782378657239391,"score_spread":0.2440334477158219,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}