{"id":"W2587005272","doi":"10.1039/c7cc00516d","title":"Mn(<scp>iv</scp>) and Mn(<scp>v</scp>)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand","year":2017,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Burnaby Hospital; Simon Fraser University","funders":"Labex; Agence Nationale de la Recherche","keywords":"Chemistry; Manganese; Redox; Ligand (biochemistry); Pincer movement; Yield (engineering); Amine gas treating; Radical; Medicinal chemistry; Electron paramagnetic resonance; Pincer ligand; Ion; Chelation; Catalysis; Inorganic chemistry; Organic chemistry; Biochemistry; Nuclear magnetic resonance; Receptor; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000945723,0.0003377845,0.0001219873,0.0001445104,0.0001219017,0.0002358541,0.0003989878,0.0002280472,0.002088587],"category_scores_gemma":[0.0001452087,0.0001014821,0.00007269749,0.000128926,0.0001594839,0.000231943,0.000376203,0.0002482685,0.0003625197],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001904791,"about_ca_system_score_gemma":0.0001165751,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002979783,"about_ca_topic_score_gemma":0.0007779722,"domain_scores_codex":[0.9999248,0.000008974835,0.00000319548,0.00002029363,0.00002048735,0.00002216694],"domain_scores_gemma":[0.9999584,0.000005926836,0.00001595087,0.000003883283,0.000005375063,0.00001048631],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009457888,0.00001381853,0.00007264724,0.0001279671,0.000006391491,0.00006395098,0.00003763674,0.0002028909,0.9944923,0.0009081863,0.0002003834,0.003779275],"study_design_scores_gemma":[0.00001187301,0.0001916638,0.0003195904,0.000006324517,0.00000551931,0.00008051649,0.00001866498,0.0006317103,0.9943751,0.00009366318,0.004260466,0.000004938818],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9839401,0.00136036,0.006345129,0.0001150531,0.00005768298,0.00004339416,0.0001842366,0.0002253455,0.007728629],"genre_scores_gemma":[0.9928597,0.0004108238,0.002874983,0.00002315233,0.0000113169,0.00001656174,0.0001445079,0.0000224917,0.003636422],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002088587,"threshold_uncertainty_score":0.006986976,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03420441800811717,"score_gpt":0.2782378657239391,"score_spread":0.2440334477158219,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}