{"id":"W2587338837","doi":"10.1021/acs.joc.6b02999","title":"Fluoride-Mediated Desulfonylative Intramolecular Cyclization to Fused and Bridged Bicyclic Compounds: A Complex Mechanism","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Bicyclic molecule; Chemistry; Diastereomer; Stereocenter; Intramolecular force; Heptane; Enantiomer; Stereochemistry; Intramolecular reaction; Enantioselective synthesis; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000536246,0.000219994,0.0004084642,0.00004660749,0.0004324859,0.0001473278,0.000829166,0.0001290363,0.0005412761],"category_scores_gemma":[0.001934195,0.000166134,0.0001083732,0.0001658807,0.0001281851,0.0001215199,0.0002147246,0.0003075086,0.00001535778],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001291414,"about_ca_system_score_gemma":0.00008281742,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002315883,"about_ca_topic_score_gemma":0.000003835576,"domain_scores_codex":[0.9986153,0.00003210054,0.0005153715,0.0001823998,0.0004187864,0.0002360697],"domain_scores_gemma":[0.9977086,0.0002725994,0.0008992371,0.0006536183,0.0002490955,0.0002169198],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007668619,0.00005230354,0.0003834566,0.00003843082,0.0002118385,0.00001635918,0.0003787296,0.00000215337,0.9964241,0.000005406749,0.0003292123,0.002081341],"study_design_scores_gemma":[0.0008437617,0.00001969911,0.002381208,0.00007794979,0.0002632405,0.0001959613,0.0005588164,0.0001615935,0.9946396,0.0002728821,0.0003848815,0.0002004593],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922923,0.0002055667,0.003885701,0.000913138,0.00005553466,0.00005171793,0.00001872677,0.00002226571,0.00255499],"genre_scores_gemma":[0.9988714,0.0001660938,0.0003264114,0.0001070023,0.0003252215,0.000001538461,0.00001383728,0.00003629423,0.0001521974],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006579043,"threshold_uncertainty_score":0.6774748,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01628545753862568,"score_gpt":0.2399008472627813,"score_spread":0.2236153897241556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}