{"id":"W2588342129","doi":"10.1039/c6cp08080d","title":"Dense ionization and subsequent non-homogeneous radical-mediated chemistry of femtosecond laser-induced low density plasma in aqueous solutions: synthesis of colloidal gold","year":2017,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Laser-Ablation Synthesis of Nanoparticles","field":"Engineering","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research","keywords":"Aqueous solution; Femtosecond; Colloidal gold; Chemistry; Homogeneous; Ionization; Colloid; Laser; Plasma; Chloride; Photochemistry; Nanoparticle; Nanotechnology; Ion; Physical chemistry; Materials science; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001299742,0.0002830151,0.0001633251,0.00009227116,0.0001046544,0.0001852033,0.0002045516,0.0002555984,0.0005141447],"category_scores_gemma":[0.0001955732,0.0001370574,0.0001649382,0.00006288608,0.000225984,0.0002840724,0.0002583601,0.0003672417,0.0001596162],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002380487,"about_ca_system_score_gemma":0.0001482854,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003031623,"about_ca_topic_score_gemma":0.0002869153,"domain_scores_codex":[0.9999115,0.00001019747,0.000004164839,0.00002571617,0.00002891926,0.00001935365],"domain_scores_gemma":[0.9999093,0.00003280081,0.00002428111,0.00001020003,0.00001455741,0.000008815079],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007372817,0.000003218602,0.00003414447,0.00001884781,0.000001570851,0.0000137565,0.00002273586,0.00005389196,0.99921,0.00005685046,0.000004863116,0.0005727827],"study_design_scores_gemma":[0.000002440108,0.00002875497,0.0001579835,6.687803e-7,0.000001479566,0.00002164103,0.000004871295,0.0003558563,0.9992654,0.00002511035,0.0001346605,0.000001186176],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908098,0.0004535634,0.0080086,0.00003449278,0.000008665726,0.00002893519,0.00002866859,0.00004618568,0.0005810824],"genre_scores_gemma":[0.9950109,0.0002449857,0.003840041,0.00001952383,0.000003798728,0.0000240128,0.00003376158,0.00001237297,0.0008105972],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005141447,"threshold_uncertainty_score":0.001727164,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01243774028601889,"score_gpt":0.2118434218798667,"score_spread":0.1994056815938478,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}