{"id":"W2589357137","doi":"10.1002/asia.201700125","title":"Stereoisomerization of Cyclic Silanols","year":2017,"lang":"en","type":"article","venue":"Chemistry - An Asian Journal","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science; New Energy and Industrial Technology Development Organization; Ministère de l'Économie, de la Science et de l'Innovation - Québec","keywords":"Chemistry; Triethylamine; Siloxane; Cleavage (geology); Chloroform; Cis–trans isomerism; Medicinal chemistry; Stereochemistry; Organic chemistry; Materials science","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002274588,0.0001373407,0.0002187622,0.00001423299,0.000391425,0.00031374,0.0007683694,0.0001089204,0.002166131],"category_scores_gemma":[0.0001572439,0.0001274947,0.00008143712,0.00002542644,0.0002093527,0.0004452678,0.00006346274,0.0001864178,0.00003106125],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002628076,"about_ca_system_score_gemma":0.0001105103,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002412015,"about_ca_topic_score_gemma":4.143778e-7,"domain_scores_codex":[0.9989638,0.00001782232,0.0003422896,0.0002024463,0.0002345128,0.0002391839],"domain_scores_gemma":[0.9984094,0.000007433514,0.0005814881,0.0006773653,0.0000975494,0.0002268008],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002014583,0.00005199843,0.003975932,0.00005144695,0.00000655407,0.00002653137,0.0002077992,0.000002019331,0.9936259,0.000003757349,0.000192983,0.001834886],"study_design_scores_gemma":[0.0004101309,0.00002248642,0.004210232,0.00006162159,0.00001391364,0.0003405378,0.0004595394,0.000009591352,0.9938614,0.000206993,0.0002617342,0.000141864],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9817262,0.00004519089,0.00006737976,0.000206247,0.0001700355,0.00002823069,0.00001393029,0.00002165252,0.01772111],"genre_scores_gemma":[0.9981002,0.0000121132,0.0003019653,0.00002167821,0.0005276549,0.000001786924,0.000009293563,0.00001531997,0.001009986],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01671113,"threshold_uncertainty_score":0.998746,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01906887069010455,"score_gpt":0.278367164504394,"score_spread":0.2592982938142894,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}