{"id":"W2591796490","doi":"10.1021/acs.joc.7b00152","title":"Lipid Peroxidation: Kinetics, Mechanisms, and Products","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":159,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; University of Ottawa","keywords":"Lipid peroxidation; Autoxidation; Polyunsaturated fatty acid; Kinetics; Chemistry; Biochemistry; Pathogenesis; Pharmacology; Oxidative stress; Biology; Fatty acid; Immunology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002898189,0.000120247,0.0001776246,0.000006100342,0.0002546475,0.0001023514,0.0006180775,0.00008192885,0.001889547],"category_scores_gemma":[0.000508868,0.00008078272,0.00003926691,0.00002202368,0.0001698891,0.0001094901,0.0001317462,0.0002961774,0.000006351037],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002716909,"about_ca_system_score_gemma":0.00006518984,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002105067,"about_ca_topic_score_gemma":9.358247e-7,"domain_scores_codex":[0.9992184,0.000007778491,0.0002775752,0.0001030197,0.0002446535,0.0001485761],"domain_scores_gemma":[0.9986652,0.00003627326,0.0005388958,0.0005258705,0.0001383747,0.00009535017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002011796,0.00004421883,0.0001047894,0.0001111843,0.00003412487,0.00001180555,0.00006047852,2.647172e-7,0.997355,0.00001625852,0.0008985476,0.001343185],"study_design_scores_gemma":[0.0004443288,0.00001655614,0.0005767168,0.0001060748,0.00006799866,0.0008452283,0.0001266242,0.000009702486,0.9939559,0.0004123479,0.003337344,0.0001012007],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906792,0.0007880973,0.00016248,0.004381234,0.0001366796,0.00001802802,0.000004210974,0.00001198725,0.003818064],"genre_scores_gemma":[0.9957322,0.0005894104,0.0004842442,0.00003460961,0.001031271,2.107549e-7,9.497492e-7,0.00001888016,0.00210823],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005052976,"threshold_uncertainty_score":0.9990228,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01183953380959728,"score_gpt":0.2220178489631137,"score_spread":0.2101783151535164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}