{"id":"W2591848653","doi":"10.1021/acs.inorgchem.6b02624","title":"π-Expansive Heteroleptic Ruthenium(II) Complexes as Reverse Saturable Absorbers and Photosensitizers for Photodynamic Therapy","year":2017,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University","funders":"Natural Sciences and Engineering Research Council of Canada; Army Research Laboratory; Canadian Institutes of Health Research; Canada Foundation for Innovation; Nova Scotia Research Innovation Trust","keywords":"Chemistry; Diimine; Phosphorescence; Ruthenium; Photochemistry; Phenazine; Excited state; Ultrafast laser spectroscopy; Density functional theory; Absorption spectroscopy; Acetonitrile; Bipyridine; Phenanthroline; Absorption (acoustics); Crystallography; Ligand (biochemistry); Absorption band; Fluorescence; Spectroscopy; Crystal structure; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001166744,0.000189544,0.0001999286,0.0001059122,0.00009354935,0.0002957016,0.0003053032,0.0002130017,0.0005910286],"category_scores_gemma":[0.00009456003,0.0001605698,0.0001051218,0.00009333808,0.0001493127,0.000159967,0.0002070428,0.0002635417,0.00018974],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002574035,"about_ca_system_score_gemma":0.00009990879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003564188,"about_ca_topic_score_gemma":0.0005826198,"domain_scores_codex":[0.999933,0.00001398396,0.00000447569,0.00001463937,0.00001864446,0.00001530037],"domain_scores_gemma":[0.9999627,0.000007141173,0.00001253834,0.000004793095,0.000004791309,0.00000806983],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001077223,0.00002634536,0.0001029269,0.00006076147,0.000007821346,0.00003667191,0.00002358812,0.0008468332,0.9957554,0.0004757344,0.00006685936,0.002489366],"study_design_scores_gemma":[0.00004017137,0.0004082075,0.0005287918,0.000005330601,0.00002457705,0.0001033253,0.00001706492,0.004203773,0.9923935,0.00006061382,0.002204385,0.00001012197],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934747,0.0009020435,0.003909377,0.00004374409,0.00001138867,0.00002746651,0.00005182319,0.00009380979,0.001485676],"genre_scores_gemma":[0.9965099,0.0003980348,0.002153644,0.00002099098,0.000003069058,0.00001480612,0.00004342365,0.00001583672,0.0008402996],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005910286,"threshold_uncertainty_score":0.001977205,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01290008923456572,"score_gpt":0.2571076041180487,"score_spread":0.2442075148834829,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}