{"id":"W2591848653","doi":"10.1021/acs.inorgchem.6b02624","title":"π-Expansive Heteroleptic Ruthenium(II) Complexes as Reverse Saturable Absorbers and Photosensitizers for Photodynamic Therapy","year":2017,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University","funders":"Natural Sciences and Engineering Research Council of Canada; Army Research Laboratory; Canadian Institutes of Health Research; Canada Foundation for Innovation; Nova Scotia Research Innovation Trust","keywords":"Chemistry; Diimine; Phosphorescence; Ruthenium; Photochemistry; Phenazine; Excited state; Ultrafast laser spectroscopy; Density functional theory; Absorption spectroscopy; Acetonitrile; Bipyridine; Phenanthroline; Absorption (acoustics); Crystallography; Ligand (biochemistry); Absorption band; Fluorescence; Spectroscopy; Crystal structure; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001744905,0.0003347515,0.0003697668,0.0000133437,0.0008802087,0.0002491068,0.0005972772,0.0002025517,0.0007556146],"category_scores_gemma":[0.0001832874,0.0003262795,0.0001032792,0.00003579247,0.000409573,0.0001833152,0.0002129226,0.0001874007,0.0001403725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008336914,"about_ca_system_score_gemma":0.0001214256,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003128705,"about_ca_topic_score_gemma":0.000007488449,"domain_scores_codex":[0.9984245,0.00001220449,0.0002766015,0.0006019052,0.0002094354,0.0004753204],"domain_scores_gemma":[0.998349,0.00008549012,0.0003053269,0.0009377246,0.000117415,0.0002051121],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001368017,0.00004535493,0.00009626365,0.0001351306,0.00002790464,0.0000195315,0.0003253367,0.000001560261,0.9975522,0.000004416338,0.001564962,0.000090541],"study_design_scores_gemma":[0.001732609,0.00005022013,0.0002155159,0.00006612908,0.00002613708,0.0002317167,0.0003207744,0.00005116349,0.9940507,0.0004007636,0.002463231,0.0003909892],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953769,0.0002287137,0.000003504509,0.0002850749,0.0002185445,0.0002679139,0.0002098807,0.0001075496,0.003301955],"genre_scores_gemma":[0.9967303,0.0001053073,0.0002217927,0.0003132731,0.0001922967,0.00003658275,0.00005094023,0.00005106566,0.002298497],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003501446,"threshold_uncertainty_score":0.9999189,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01290008923456572,"score_gpt":0.2571076041180487,"score_spread":0.2442075148834829,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}