{"id":"W2592721731","doi":"10.1016/j.jms.2017.02.016","title":"Giant K-doubling and in-plane/out-of-plane mixing in the asymmetric methyl-bending bands of CH3SH","year":2017,"lang":"en","type":"article","venue":"Journal of Molecular Spectroscopy","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); University of Saskatchewan; University of New Brunswick","funders":"Basic Energy Sciences; National Research Council Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; University of Saskatchewan","keywords":"Physics; Asymmetry; Spectral line; Coupling (piping); Bending; Atomic physics; Plane (geometry); Mixing (physics); Molecular physics; Geometry; Materials science; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001389324,0.0002087499,0.00009190699,0.0004801574,0.0003282583,0.000176458,0.0002659715,0.0002085134,0.001488484],"category_scores_gemma":[0.000220307,0.0002194971,0.0001612572,0.0003034388,0.0004157939,0.0003508643,0.0003668412,0.000312555,0.0001492196],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001839987,"about_ca_system_score_gemma":0.0001231001,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009135442,"about_ca_topic_score_gemma":0.001731366,"domain_scores_codex":[0.9999,0.00000938697,0.000002893248,0.00001831341,0.0000338573,0.00003556901],"domain_scores_gemma":[0.9998099,0.00004323146,0.00006867156,0.00002278195,0.00002133443,0.00003404644],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000207049,0.00001979042,0.006229637,0.00002886864,0.00001843536,0.0002899577,0.0001975875,0.000339301,0.9890042,0.000524665,0.00004490444,0.003095586],"study_design_scores_gemma":[0.00002537224,0.0002035596,0.1220004,0.00001007255,0.00002637479,0.00120726,0.0003990374,0.00428697,0.8691567,0.001563946,0.001086997,0.00003325099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978346,0.00005640292,0.001191862,0.00002446978,0.000002955087,0.000002856035,0.0000307741,0.00001927606,0.0008367655],"genre_scores_gemma":[0.9992121,0.00001803202,0.0003669409,0.00001111604,0.000001110996,0.000002444986,0.00002958974,0.000005787064,0.0003528414],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001488484,"threshold_uncertainty_score":0.004979432,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01623538245673216,"score_gpt":0.3066446319653863,"score_spread":0.2904092495086541,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}