{"id":"W2594577686","doi":"10.1039/c7ra00710h","title":"Supramolecular catalysis in the methylation of meta-phenylene ethynylene foldamer containing N,N-dimethylaminopyridine","year":2017,"lang":"en","type":"article","venue":"RSC Advances","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Natural Science Foundation of Zhejiang Province; National Natural Science Foundation of China; National Supercomputer Centre in Guangzhou","keywords":"Chemistry; Supramolecular chemistry; Foldamer; Sulfonate; Catalysis; Stereochemistry; Methylation; Polymer chemistry; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006818389,0.0002173489,0.0001727019,0.00005114462,0.0001415888,0.0001883373,0.0002291075,0.0001941626,0.002041895],"category_scores_gemma":[0.0001182713,0.000119264,0.0001198751,0.00005396578,0.0001440538,0.0002168511,0.0002153086,0.0002905224,0.0003183417],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001809812,"about_ca_system_score_gemma":0.0001393275,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004775602,"about_ca_topic_score_gemma":0.0007269599,"domain_scores_codex":[0.9999542,0.000005118947,0.00000163505,0.00001143175,0.000009337931,0.00001824406],"domain_scores_gemma":[0.9999788,0.000006383219,0.000005435076,0.000002574345,0.000001980365,0.000004742122],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001343394,0.00003693646,0.0003211479,0.0001618856,0.00001294985,0.0004400457,0.00008908902,0.002799299,0.9864889,0.004499583,0.0002412894,0.004774615],"study_design_scores_gemma":[0.00004010172,0.0005976249,0.001541565,0.000009494315,0.00002006903,0.0002309943,0.00005652931,0.02141264,0.9722486,0.0007475927,0.003077787,0.00001700652],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915611,0.0004972982,0.003467406,0.0000761073,0.0000266073,0.00001566509,0.00003991533,0.00006648055,0.004249434],"genre_scores_gemma":[0.9981614,0.0001395287,0.0008091288,0.0000120329,0.000002478111,0.000008171751,0.00002449426,0.000005786588,0.0008369673],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002041895,"threshold_uncertainty_score":0.006830871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02609244617786304,"score_gpt":0.3043649543135433,"score_spread":0.2782725081356802,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}