{"id":"W2599702333","doi":"10.1002/chem.201701226","title":"Synthesis of <i>ortho</i>‐Azophenols by Formal Dehydrogenative Coupling of Phenols and Hydrazines or Hydrazides","year":2017,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydrazine (antidepressant); Hydrazide; Chemistry; Isomerization; Catalysis; Reagent; Phenols; Chromophore; Combinatorial chemistry; Stoichiometry; Organic synthesis; Molecular switch; Condensation; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000096025,0.0003557161,0.0001212081,0.0001400178,0.0001273886,0.0001839992,0.0002507446,0.0001371676,0.001527875],"category_scores_gemma":[0.0001151224,0.0001497136,0.0001711226,0.0001477883,0.0002081898,0.0002556891,0.0002837535,0.0003654179,0.0005872275],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002386261,"about_ca_system_score_gemma":0.0003120807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005344096,"about_ca_topic_score_gemma":0.0009979726,"domain_scores_codex":[0.9999251,0.000009325797,0.000004813593,0.0000173354,0.00001610305,0.00002734654],"domain_scores_gemma":[0.9999495,0.000008199446,0.00001389323,0.000009869143,0.000006388074,0.00001212419],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003662394,0.00002168802,0.0001724404,0.0001823517,0.000009196659,0.0001718009,0.00006702985,0.0003459628,0.9878032,0.003089961,0.0002860604,0.007813691],"study_design_scores_gemma":[0.000007946927,0.00009696669,0.0007091776,0.000005465459,0.000008508337,0.0001742932,0.00002151069,0.0006128951,0.9891241,0.0003084211,0.008921225,0.000009654937],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9204023,0.002277321,0.05186639,0.0002975101,0.0001981022,0.0001143196,0.0008367256,0.000582539,0.02342471],"genre_scores_gemma":[0.9839236,0.00156464,0.01099018,0.00004666926,0.00001578677,0.00003672616,0.0002452045,0.00006077103,0.003116316],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001527875,"threshold_uncertainty_score":0.005111277,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02723777543422544,"score_gpt":0.2759165466567963,"score_spread":0.2486787712225708,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}