{"id":"W2603186877","doi":"10.1038/nchem.2751","title":"Coherent ultrafast lattice-directed reaction dynamics of triiodide anion photodissociation","year":2017,"lang":"en","type":"article","venue":"Nature Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"Engineering and Physical Sciences Research Council; Max-Planck-Gesellschaft; Alexander von Humboldt-Stiftung","keywords":"Chemistry; Triiodide; Photochemistry; Photodissociation; Ultrafast laser spectroscopy; Ion; Intermolecular force; Reaction dynamics; Radical; Spectroscopy; Chemical reaction; Chemical physics; Molecule; Physical chemistry; Organic chemistry; Electrolyte","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001866138,0.0001918508,0.000190067,0.0002107466,0.0002657865,0.0005390772,0.0005279344,0.0002761045,0.003090952],"category_scores_gemma":[0.0006038446,0.0001572285,0.0001019193,0.00018262,0.0004762464,0.0006584511,0.0003832213,0.0007057438,0.0001969272],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007509606,"about_ca_system_score_gemma":0.0003741076,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001112949,"about_ca_topic_score_gemma":0.001431449,"domain_scores_codex":[0.999925,0.000007055436,0.000001907818,0.00002163483,0.00002267718,0.00002176812],"domain_scores_gemma":[0.9997844,0.00009582152,0.00004483737,0.00001846912,0.00002099246,0.00003554632],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005391867,0.0002196255,0.002800079,0.0000720875,0.00003457493,0.0002362655,0.0005433778,0.007143803,0.9630427,0.01256956,0.0005500504,0.01224868],"study_design_scores_gemma":[0.0002599505,0.0003883012,0.01417463,0.00002638444,0.00003885507,0.0001712678,0.0002907695,0.3361321,0.6404653,0.004632652,0.003316429,0.0001032816],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908765,0.0001489341,0.005449974,0.0001323204,0.00003177383,0.00001024104,0.00005785951,0.00008973883,0.003202788],"genre_scores_gemma":[0.9980972,0.00003677832,0.0007354633,0.00001689512,0.000005190506,0.000005524453,0.0000389542,0.00001685571,0.001046999],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003090952,"threshold_uncertainty_score":0.01034027,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007504911364369055,"score_gpt":0.2693201407503185,"score_spread":0.2618152293859494,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}