{"id":"W2603776760","doi":"10.1107/s2414314617004527","title":"Bromidocarbonyl{(1<i>S</i>,2<i>S</i>)-<i>N</i>-[2-(dicyclohexylphosphanyl)ethylidenyl]-<i>N</i>′-[2-(diphenylphosphanyl)ethyl]-1,2-diphenylethane-1,2-diamine}iron(II) tetraphenylborate","year":2017,"lang":"en","type":"article","venue":"IUCrData","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto","keywords":"Chemistry; Diastereomer; Molecule; Solvent; Ligand (biochemistry); Crystallography; Crystal structure; Diethyl ether; Octahedron; Tetraphenylborate; Electron density; Ether; Diamine; Stereochemistry; Ion; Electron; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001662384,0.0003075234,0.0003456248,0.0001197196,0.0002308001,0.0001986888,0.0007084149,0.000258701,0.008735894],"category_scores_gemma":[0.0001534793,0.0002472925,0.0001006431,0.0001999425,0.0002025747,0.000270012,0.0002889131,0.00045312,0.002530471],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003443088,"about_ca_system_score_gemma":0.0003356036,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008048855,"about_ca_topic_score_gemma":0.001576834,"domain_scores_codex":[0.9998757,0.00001695686,0.000006816578,0.00003043945,0.00002867884,0.00004142146],"domain_scores_gemma":[0.9999353,0.00001245436,0.00002046632,0.00001072794,0.000007347904,0.00001367612],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001192725,0.00005753283,0.0002907738,0.0008576578,0.00002962474,0.000246286,0.0000801007,0.0004940685,0.9751896,0.001782355,0.004200774,0.01557857],"study_design_scores_gemma":[0.0003995185,0.000801174,0.002139261,0.00005004344,0.00003393906,0.0005494753,0.0000745087,0.001300506,0.9358643,0.0003446283,0.05839805,0.00004475605],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9305816,0.003465846,0.01652573,0.0006049501,0.0004408665,0.000196117,0.003725174,0.002252134,0.04220763],"genre_scores_gemma":[0.9705128,0.001760664,0.008598693,0.000279178,0.00003125188,0.000151393,0.002423585,0.0002694082,0.01597301],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008735894,"threshold_uncertainty_score":0.02922446,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04198151099510308,"score_gpt":0.3016979871929768,"score_spread":0.2597164761978737,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}