{"id":"W2603776760","doi":"10.1107/s2414314617004527","title":"Bromidocarbonyl{(1<i>S</i>,2<i>S</i>)-<i>N</i>-[2-(dicyclohexylphosphanyl)ethylidenyl]-<i>N</i>′-[2-(diphenylphosphanyl)ethyl]-1,2-diphenylethane-1,2-diamine}iron(II) tetraphenylborate","year":2017,"lang":"en","type":"article","venue":"IUCrData","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto","keywords":"Chemistry; Diastereomer; Molecule; Solvent; Ligand (biochemistry); Crystallography; Crystal structure; Diethyl ether; Octahedron; Tetraphenylborate; Electron density; Ether; Diamine; Stereochemistry; Ion; Electron; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.001830355,0.001549357,0.002295231,0.0004304657,0.003330129,0.001019487,0.003359056,0.0006726942,0.002412883],"category_scores_gemma":[0.002065351,0.001333574,0.0009004936,0.0005053073,0.001530902,0.001607764,0.002338487,0.001417307,0.0008159274],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002069295,"about_ca_system_score_gemma":0.0005350733,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001370996,"about_ca_topic_score_gemma":0.0002156651,"domain_scores_codex":[0.9915295,0.0002719126,0.001808648,0.002332341,0.001880596,0.002176984],"domain_scores_gemma":[0.9884736,0.0003544647,0.001193695,0.008033023,0.0005839139,0.001361288],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0037491,0.002473342,0.04482792,0.001509996,0.001629343,0.001410022,0.001362287,0.00002176109,0.7882017,0.004145985,0.1035331,0.04713534],"study_design_scores_gemma":[0.008652601,0.001948209,0.07489707,0.001238481,0.00151075,0.0006843766,0.0003605304,0.0005387506,0.3454261,0.002810032,0.5588088,0.003124308],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8888806,0.01503482,0.0003092501,0.009551668,0.003354577,0.002657644,0.0007128688,0.001049143,0.07844941],"genre_scores_gemma":[0.9663911,0.002106499,0.005917893,0.004243413,0.001584836,0.0002421815,0.0003814565,0.0003797017,0.01875289],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4552757,"threshold_uncertainty_score":0.999962,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04198151099510308,"score_gpt":0.3016979871929768,"score_spread":0.2597164761978737,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}