{"id":"W2603967212","doi":"10.1063/1.4976980","title":"1H–2H cross-polarization NMR in fast spinning solids by adiabatic sweeps","year":2017,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; Israel Science Foundation; National Science Foundation","keywords":"Spinning; Adiabatic process; Materials science; Polarization (electrochemistry); Physics; Chemistry; Thermodynamics; Physical chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005033519,0.000338552,0.0002023252,0.0002974019,0.0002584025,0.0003426722,0.0003559712,0.0002793063,0.001069531],"category_scores_gemma":[0.0003303738,0.0002788683,0.0001375051,0.0004399647,0.0007599997,0.0006189537,0.0006249046,0.0006383939,0.0003190606],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001915051,"about_ca_system_score_gemma":0.0001977615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003034504,"about_ca_topic_score_gemma":0.0004786266,"domain_scores_codex":[0.9997445,0.00008949556,0.000006766037,0.00005856145,0.00006471452,0.00003598417],"domain_scores_gemma":[0.9998381,0.00006447612,0.00003625883,0.0000335435,0.00001463297,0.00001289277],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007090132,0.00002609543,0.0002795278,0.0001463067,0.00001214379,0.0001735769,0.0001777929,0.003026271,0.9645975,0.01203318,0.0002295731,0.01922696],"study_design_scores_gemma":[0.00003752681,0.0004674166,0.002302608,0.00002772508,0.00002055276,0.0004497202,0.0001002057,0.04142841,0.931632,0.01077769,0.01270087,0.0000551468],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8130622,0.003249058,0.1741824,0.0002431896,0.000095503,0.00006686325,0.0001898199,0.0004186772,0.008492424],"genre_scores_gemma":[0.9497162,0.003152957,0.04425571,0.00006043254,0.0001244414,0.00007574166,0.0001652043,0.00005279829,0.002396571],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001069531,"threshold_uncertainty_score":0.003577888,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01524937782805456,"score_gpt":0.3155579418296627,"score_spread":0.3003085640016082,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}