{"id":"W2604178871","doi":"10.1002/ejoc.201700201","title":"Cycloadditions of Donor–Acceptor Cyclopropanes and Nitriles","year":2017,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":137,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Cycloaddition; Lewis acids and bases; Acceptor; Nitrile; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003345684,0.0006067436,0.0002375598,0.000383359,0.0003095961,0.0003099387,0.0004472364,0.0002429309,0.005007064],"category_scores_gemma":[0.0002618688,0.0002434201,0.0003333713,0.0003256298,0.0002556299,0.0006024265,0.0006560489,0.00100733,0.001041215],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004109365,"about_ca_system_score_gemma":0.0002859838,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000316401,"about_ca_topic_score_gemma":0.0008813617,"domain_scores_codex":[0.9997769,0.00004103122,0.00001426018,0.00004710812,0.00005248134,0.00006828335],"domain_scores_gemma":[0.9999175,0.00002634118,0.00001605535,0.00001549914,0.00001126244,0.00001336747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000395362,0.0002736366,0.0003619099,0.0009818497,0.00007150152,0.001618285,0.0003427028,0.002700724,0.9150804,0.04615334,0.002437624,0.02958277],"study_design_scores_gemma":[0.00004041523,0.0006161952,0.0006577502,0.00004502239,0.00002749152,0.0006930709,0.00005882075,0.002423575,0.9629136,0.001556049,0.03093343,0.00003461972],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7884275,0.01158339,0.06074889,0.0006656717,0.000907236,0.0006828679,0.001077851,0.0004549532,0.1354516],"genre_scores_gemma":[0.9528061,0.01066746,0.01435246,0.0002045212,0.0001105451,0.0003353315,0.0004834193,0.00006799895,0.02097217],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005007064,"threshold_uncertainty_score":0.01675028,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01154297944779385,"score_gpt":0.2191088733879654,"score_spread":0.2075658939401716,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}