{"id":"W2604250514","doi":"10.1016/j.carres.2017.04.007","title":"Studies on the 6-homologation of β-D-idopyranosides","year":2017,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"Alberta Glycomics Centre; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Innovates; Government of Alberta","keywords":"Chemistry; Regioselectivity; Steric effects; Swern oxidation; Stereochemistry; Anomer; Ring (chemistry); Flexibility (engineering); Anomeric effect; Wittig reaction; Organic chemistry; Catalysis; Dimethyl sulfoxide","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001568864,0.0001571454,0.0002698756,0.00007126155,0.001079648,0.0001281631,0.0009708439,0.0001381649,0.0003637898],"category_scores_gemma":[0.004703894,0.000105164,0.0001246921,0.0001253899,0.001361122,0.0000916572,0.0003009982,0.0004814066,0.00005960181],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001000856,"about_ca_system_score_gemma":0.00009077133,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005689201,"about_ca_topic_score_gemma":0.00001434275,"domain_scores_codex":[0.9982341,0.0001128337,0.0003004433,0.0003306121,0.0006367553,0.0003852427],"domain_scores_gemma":[0.9960338,0.001594114,0.0002002141,0.001608498,0.0004879361,0.00007537776],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005794408,0.00004932695,0.0004380018,0.0001545547,0.0001139982,0.0000223919,0.0005088003,0.00001334191,0.9924886,0.004851544,0.0006513224,0.0006501898],"study_design_scores_gemma":[0.0001390169,0.000021714,0.00007688632,0.0001893811,0.0000146905,0.000001536172,0.001746466,0.0001594832,0.9927139,0.004458121,0.0003720408,0.0001067866],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.923988,0.0003247213,2.866163e-7,0.001994658,0.00009855056,0.0000784786,0.00001660716,0.00002568972,0.07347295],"genre_scores_gemma":[0.9970113,0.0002612159,0.000007064689,0.00001629568,0.0002407683,0.00008680489,0.00000411359,0.00002107693,0.002351363],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07302324,"threshold_uncertainty_score":0.8303885,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.2843209442606048,"score_gpt":0.4318201982031399,"score_spread":0.1474992539425351,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}