{"id":"W2604406681","doi":"10.1002/ajoc.201700130","title":"Unsupported Nanoporous Gold‐Catalyzed Chemoselective Reduction of α,β‐Unsaturated Aldehydes Using Formic Acid as Hydrogen Source","year":2017,"lang":"en","type":"article","venue":"Asian Journal of Organic Chemistry","topic":"Nanoporous metals and alloys","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Population and Public Health; King Saud University; National Natural Science Foundation of China","keywords":"Chemistry; Formic acid; Catalysis; Nanoporous; Selectivity; Allylic rearrangement; Hydrogen; Leaching (pedology); Chemoselectivity; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001170754,0.000286613,0.0001763669,0.0001602682,0.0001182066,0.0001519371,0.0003596127,0.000296186,0.000612294],"category_scores_gemma":[0.0001419466,0.0001689454,0.0001750622,0.00009225481,0.0001676117,0.000291385,0.0002708753,0.0002288444,0.0003298787],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002426434,"about_ca_system_score_gemma":0.0001486255,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007566491,"about_ca_topic_score_gemma":0.001943234,"domain_scores_codex":[0.9998755,0.0000112214,0.00001093258,0.0000305682,0.00004399005,0.000027725],"domain_scores_gemma":[0.9999249,0.0000122844,0.00001792783,0.00001196346,0.00001961457,0.00001327867],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002612865,0.000006762282,0.00006140307,0.00005199868,0.000006377014,0.00006442453,0.00001279484,0.0001077212,0.9978222,0.0000891134,0.00005724307,0.001693838],"study_design_scores_gemma":[0.000002190031,0.00003527779,0.0002642814,0.000001775242,0.000004750033,0.00005851292,0.000006731498,0.0004979401,0.9982674,0.00001407787,0.0008438618,0.000003210477],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9793161,0.001946628,0.01336451,0.0001176657,0.00009624839,0.00004313457,0.0003292542,0.0003408038,0.004445676],"genre_scores_gemma":[0.9905866,0.0005192232,0.00691896,0.00004114724,0.00000952212,0.00001857111,0.0001783982,0.00001638864,0.001711148],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007566491,"threshold_uncertainty_score":0.002048314,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01119800784770755,"score_gpt":0.2470708800258573,"score_spread":0.2358728721781498,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}