{"id":"W2605429967","doi":"10.1039/c7cc01168g","title":"Revisiting the Juliá–Colonna enantioselective epoxidation: supramolecular catalysis in water","year":2017,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Chemistry and Chemical Engineering","field":"Environmental Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada","keywords":"Enantioselective synthesis; Supramolecular chemistry; Catalysis; Chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001955093,0.00009265084,0.0001015942,0.000007061667,0.0004380583,0.00007250548,0.001524545,0.00006228845,0.0001700113],"category_scores_gemma":[0.0003097048,0.00006555563,0.00005840255,0.00008512525,0.0003576612,0.0001475907,0.001080627,0.0003158141,0.0001135],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001152879,"about_ca_system_score_gemma":0.000004200803,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001061564,"about_ca_topic_score_gemma":0.000009610147,"domain_scores_codex":[0.9993088,0.00002324293,0.000178406,0.0001759925,0.0001151341,0.0001984502],"domain_scores_gemma":[0.9980028,0.00009216111,0.00005602674,0.001789601,0.00001013023,0.00004924365],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000002071607,0.00002504753,0.002203737,0.000004863808,0.000007454923,0.000001062976,0.0002079882,0.00007752366,0.9956716,0.00009062031,0.00006939632,0.001638681],"study_design_scores_gemma":[0.0001262304,0.000001247934,0.002373558,0.0000197905,0.00001513232,0.000005347557,0.00003692729,0.002071661,0.9859177,0.0004864176,0.008821071,0.0001249154],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9580188,0.00008016682,0.0001506211,0.00900018,0.00001256254,0.0001046077,0.000001258362,0.00003227931,0.0325995],"genre_scores_gemma":[0.9990274,0.00003179875,0.0006097605,0.00007550932,0.00003595838,0.00003090611,0.00004630774,0.000008405526,0.0001339695],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04100856,"threshold_uncertainty_score":0.3369235,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01343203858307361,"score_gpt":0.2514621663392895,"score_spread":0.2380301277562159,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}