{"id":"W2605475406","doi":"10.1016/j.phytochem.2017.04.009","title":"Epoxynemanione A, nemanifuranones A–F, and nemanilactones A–C, from Nemania serpens, an endophytic fungus isolated from Riesling grapevines","year":2017,"lang":"en","type":"article","venue":"Phytochemistry","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":26,"is_retracted":false,"has_abstract":false,"ca_institutions":"Agriculture and Agri-Food Canada; McMaster University","funders":"","keywords":"Stereochemistry; Polyketide; Two-dimensional nuclear magnetic resonance spectroscopy; Botany; Metabolite; Biology; Benzoic acid; Fungus; Chemistry; Biosynthesis; Biochemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001147464,0.0004728298,0.0007283891,0.00004441959,0.0006551128,0.0003224323,0.0003886326,0.0002856284,0.0006307475],"category_scores_gemma":[0.0003210247,0.0003956113,0.0001383007,0.00006916784,0.000259071,0.0004192473,0.0002158245,0.0003980607,0.00004167401],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003482834,"about_ca_system_score_gemma":0.00006129609,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001772955,"about_ca_topic_score_gemma":0.0001520749,"domain_scores_codex":[0.9978715,0.00002895279,0.00045093,0.0009519841,0.0002655525,0.0004310485],"domain_scores_gemma":[0.9975699,0.0001055729,0.0003816225,0.001439181,0.0001878404,0.0003159144],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005111477,0.0001448433,0.007910557,0.0001966423,0.0001884396,0.0001402547,0.0001811473,2.95698e-7,0.9872155,0.00001156424,0.0004781637,0.003021504],"study_design_scores_gemma":[0.001872988,0.0001381149,0.06592886,0.0006149654,0.0005256914,0.0001339656,0.0002891405,0.0003541044,0.9268714,0.0008907123,0.001696213,0.0006838163],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924991,0.003662651,0.00001945775,0.001869264,0.0003656415,0.0003663632,0.0001486494,0.0001654386,0.0009034721],"genre_scores_gemma":[0.9949538,0.0004618758,0.001162349,0.0002877922,0.002009357,0.000004849812,0.0002906665,0.00006287557,0.0007664689],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06034401,"threshold_uncertainty_score":0.9998496,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0181208077512006,"score_gpt":0.266537732508415,"score_spread":0.2484169247572144,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}