{"id":"W2605475406","doi":"10.1016/j.phytochem.2017.04.009","title":"Epoxynemanione A, nemanifuranones A–F, and nemanilactones A–C, from Nemania serpens, an endophytic fungus isolated from Riesling grapevines","year":2017,"lang":"en","type":"article","venue":"Phytochemistry","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":26,"is_retracted":false,"has_abstract":false,"ca_institutions":"Agriculture and Agri-Food Canada; McMaster University","funders":"","keywords":"Stereochemistry; Polyketide; Two-dimensional nuclear magnetic resonance spectroscopy; Botany; Metabolite; Biology; Benzoic acid; Fungus; Chemistry; Biosynthesis; Biochemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005445716,0.0002997295,0.0001127803,0.0002734739,0.0001194945,0.0001220963,0.00007523005,0.0001195679,0.0005840676],"category_scores_gemma":[0.00007240305,0.00008088468,0.000142352,0.0001190733,0.0001070718,0.0001295416,0.0001186164,0.0001640969,0.0001923403],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009287046,"about_ca_system_score_gemma":0.0001337636,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006051992,"about_ca_topic_score_gemma":0.001121904,"domain_scores_codex":[0.9999708,0.000004934957,0.000003436073,0.000006735555,0.000007770341,0.000006356603],"domain_scores_gemma":[0.9999542,0.000007287934,0.000007093729,0.000006493128,0.000008843261,0.00001598154],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007591714,0.000009096873,0.0003882049,0.00002254682,0.000003049545,0.0001745719,0.00002136226,0.00004923402,0.9973794,0.00002322773,0.00001074551,0.001842514],"study_design_scores_gemma":[0.00002115236,0.000593478,0.05041202,0.00002368356,0.00002914911,0.001093376,0.0001531084,0.0002870323,0.941771,0.0001278683,0.005477317,0.00001080645],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949253,0.001117003,0.0009476215,0.00003168994,0.00001267709,0.00002250314,0.0003920976,0.00001353331,0.00253751],"genre_scores_gemma":[0.9945427,0.0007356331,0.001337511,0.00002873766,0.000007755383,0.000009331353,0.0009361749,0.000004996356,0.002397193],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006051992,"threshold_uncertainty_score":0.0019539,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0181208077512006,"score_gpt":0.266537732508415,"score_spread":0.2484169247572144,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}