{"id":"W2605832538","doi":"10.1149/07711.1503ecst","title":"(Keynote) Electroreduction of Nitrocyclopropanes and Nitrophenyl Cyclopropanes: Mechanism of Cleavage of the Radical Anion","year":2017,"lang":"en","type":"article","venue":"ECS Transactions","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Université de Sherbrooke","keywords":"Chemistry; Heterolysis; Homolysis; Cleavage (geology); Photochemistry; Radical ion; Radical; Bond cleavage; Ion; Organic chemistry; Catalysis; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005834134,0.0001076649,0.0001848526,0.00007183274,0.0001979493,0.000010074,0.0001505034,0.00009009985,0.00002550859],"category_scores_gemma":[0.00001368322,0.00008466614,0.000100867,0.00008873077,0.0001980644,0.00009149069,0.000006497881,0.0001573777,2.523723e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001306541,"about_ca_system_score_gemma":0.00001759927,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001473379,"about_ca_topic_score_gemma":0.00004278385,"domain_scores_codex":[0.9993752,0.00002481964,0.0002330313,0.0001075385,0.0001453247,0.0001140929],"domain_scores_gemma":[0.999442,0.00001320011,0.0001053255,0.0003646102,0.0000425692,0.00003225755],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002750548,0.00003310918,0.00009090787,0.0001296324,0.00007275065,4.56744e-7,0.0001729816,0.0009401574,0.9940518,0.0008693264,0.00002929286,0.003582069],"study_design_scores_gemma":[0.0003104324,0.00006553123,0.008251381,0.00003817982,0.0001016627,0.0000349684,0.00008738097,0.0009445104,0.9879676,0.001857758,0.0002526834,0.00008791456],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9486827,0.0001933978,0.04982002,0.00006738499,0.0004141076,0.0001750378,0.00002368153,0.00003216389,0.0005915213],"genre_scores_gemma":[0.9988783,0.0003155724,0.0007120236,0.000002034352,0.00002993,0.000007137885,0.000001378603,0.00001851594,0.00003512757],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0501956,"threshold_uncertainty_score":0.3452585,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004717718257371234,"score_gpt":0.1872612313307117,"score_spread":0.1825435130733404,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}