{"id":"W2606562005","doi":"10.1016/j.cplett.2017.04.035","title":"Non-radiative relaxation dynamics of pyrrole following excitation in the range 249.5–200 nm","year":2017,"lang":"en","type":"article","venue":"Chemical Physics Letters","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"Engineering and Physical Sciences Research Council","keywords":"Excitation; Atomic physics; Relaxation (psychology); Population; Radiative transfer; Spectroscopy; Chemistry; Range (aeronautics); Dynamics (music); Molecular physics; Physics; Materials science; Optics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001865691,0.0001874155,0.0001418228,0.0002013464,0.0003456211,0.0002852894,0.0004566551,0.0002930843,0.006249788],"category_scores_gemma":[0.0004236442,0.0001371166,0.0001384088,0.0001782786,0.0003467718,0.000449816,0.0001469019,0.0005522665,0.0004552703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000450337,"about_ca_system_score_gemma":0.0001830074,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001839583,"about_ca_topic_score_gemma":0.002112489,"domain_scores_codex":[0.9999064,0.000009361891,0.000001860073,0.00003006784,0.00001907341,0.00003319683],"domain_scores_gemma":[0.9997204,0.0001691427,0.00004738648,0.00001444354,0.00002354847,0.00002495016],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009970577,0.0001597695,0.001174041,0.00009873092,0.0000181491,0.0004345771,0.0003587183,0.0007478488,0.9900711,0.0007388383,0.000342263,0.004858858],"study_design_scores_gemma":[0.0001063439,0.001008025,0.06999717,0.00004356379,0.0000456542,0.0005694529,0.0004960114,0.01927079,0.9050463,0.0005698522,0.002777997,0.00006887716],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961514,0.0002473817,0.0007579226,0.00005187499,0.0000121893,0.000006434638,0.00009896676,0.00003577854,0.002637974],"genre_scores_gemma":[0.9980167,0.00008985306,0.0002221585,0.00001846041,0.000004324214,0.000005593741,0.0001596915,0.00001007912,0.001473112],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006249788,"threshold_uncertainty_score":0.02090764,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01190341703645538,"score_gpt":0.245591631217525,"score_spread":0.2336882141810696,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}