{"id":"W2607248489","doi":"10.1021/acs.accounts.6b00516","title":"Structure and Dynamics of Individual Diastereomeric Complexes on Platinum: Surface Studies Related to Heterogeneous Enantioselective Catalysis","year":2017,"lang":"en","type":"article","venue":"Accounts of Chemical Research","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Lundbeckfonden; Natur og Univers, Det Frie Forskningsråd; Centre in Green Chemistry and Catalysis; Fonds Québécois de la Recherche sur la Nature et les Technologies; Canada Foundation for Innovation","keywords":"Enantioselective synthesis; Diastereomer; Platinum; Catalysis; Chemistry; Dynamics (music); Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001278005,0.0002598352,0.0003028174,0.0002764603,0.0002668943,0.0005877892,0.0005804767,0.0004735114,0.00198426],"category_scores_gemma":[0.0003550173,0.0002576018,0.0003192343,0.0002469367,0.000425624,0.0003676856,0.0003051589,0.0005349337,0.0002483579],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000746952,"about_ca_system_score_gemma":0.0001255229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002132062,"about_ca_topic_score_gemma":0.001287082,"domain_scores_codex":[0.9998326,0.000009826838,0.000005916751,0.00004660538,0.00005825323,0.00004666827],"domain_scores_gemma":[0.9998947,0.00002752546,0.00002697305,0.00001363795,0.00002124076,0.00001598713],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003299886,0.0001262244,0.006367829,0.0001878849,0.00008286516,0.0005738221,0.0004609337,0.01494461,0.9635198,0.003836988,0.0006273492,0.008941652],"study_design_scores_gemma":[0.00006948194,0.0004946402,0.02545618,0.00001821608,0.00006522067,0.0003423108,0.0004559259,0.1422938,0.8264622,0.001278197,0.003014063,0.0000498345],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955682,0.0003567279,0.001569511,0.00008915469,0.000008028537,0.00001067895,0.0001269282,0.00004358354,0.002227217],"genre_scores_gemma":[0.9986941,0.0001925394,0.000509077,0.00001345908,0.000003344776,0.000006752447,0.0001381876,0.0000132992,0.000429242],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002132062,"threshold_uncertainty_score":0.00663805,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04296272920855621,"score_gpt":0.3504948867358187,"score_spread":0.3075321575272625,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}