{"id":"W2607630413","doi":"10.1039/c6sc05624e","title":"Comparison of structural dynamics and coherence of d–d and MLCT light-induced spin state trapping","year":2017,"lang":"en","type":"article","venue":"Chemical Science","topic":"Quantum optics and atomic interactions","field":"Physics and Astronomy","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Regional Development Fund; Région Bretagne; Institut Universitaire de France; H2020 European Research Council; Agence Nationale de la Recherche; Centre National de la Recherche Scientifique; European Commission; Institut national de la recherche scientifique","keywords":"Trapping; Coherence (philosophical gambling strategy); Dynamics (music); Chemical physics; Spin (aerodynamics); Materials science; Physics; Molecular physics; Chemistry; Optics; Quantum mechanics; Thermodynamics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000124387,0.000214084,0.0001984592,0.0003104696,0.0002126222,0.0003215331,0.0003407527,0.0002566616,0.003524348],"category_scores_gemma":[0.0004880692,0.0001044474,0.0001611593,0.0002463007,0.00032037,0.0003282505,0.0001977127,0.0003801617,0.0001567293],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005730161,"about_ca_system_score_gemma":0.0003057247,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001718956,"about_ca_topic_score_gemma":0.002468723,"domain_scores_codex":[0.9999475,0.000004662671,0.000003896507,0.00001231023,0.00001624793,0.00001537914],"domain_scores_gemma":[0.999823,0.00008246695,0.00002654203,0.00002039501,0.0000272117,0.00002032178],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005253245,0.0002531827,0.005734141,0.0005822454,0.00006018647,0.0003259249,0.0003121294,0.04030778,0.9111162,0.02446659,0.0008271762,0.01548901],"study_design_scores_gemma":[0.00004738523,0.0004630184,0.01008956,0.00004374893,0.00004618909,0.0001319085,0.0001895198,0.4124475,0.5698161,0.004245917,0.002404561,0.00007451318],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915001,0.0001519603,0.004896111,0.00006738628,0.00001240385,0.00001368535,0.0002298902,0.0000775277,0.00305104],"genre_scores_gemma":[0.9983016,0.00005625571,0.001061947,0.00001141916,0.000001544453,0.00001154765,0.0001473543,0.00001121256,0.0003969909],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003524348,"threshold_uncertainty_score":0.0117901,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02480307289447875,"score_gpt":0.3522399019682612,"score_spread":0.3274368290737824,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}