{"id":"W2608893679","doi":"10.1039/c7dt01039g","title":"Electrocatalytic generation of H<sub>2</sub> from neutral water in acetonitrile using manganese polypyridyl complexes with ligand assistance","year":2017,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Acetonitrile; Manganese; Chemistry; Ligand (biochemistry); Inorganic chemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001050908,0.0003912502,0.0001719253,0.00007879805,0.0001262086,0.0002622301,0.000338867,0.0002472734,0.00110535],"category_scores_gemma":[0.0001685452,0.0001249773,0.0001088446,0.0001180454,0.0002292052,0.0002063103,0.0001562117,0.0003155268,0.0002448444],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003471169,"about_ca_system_score_gemma":0.0001645619,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001685382,"about_ca_topic_score_gemma":0.003414513,"domain_scores_codex":[0.99991,0.000007822464,0.000004930537,0.00002902725,0.00002613936,0.00002212108],"domain_scores_gemma":[0.9999529,0.00001350946,0.00001129372,0.000004957682,0.000008639731,0.00000867367],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005963701,0.0000112991,0.0001566447,0.00005037712,0.00000518442,0.0000369674,0.00001784717,0.00005186707,0.9971191,0.0001807296,0.00007432712,0.002236018],"study_design_scores_gemma":[0.000005336101,0.00004209515,0.0002896903,0.000001535159,0.000003546957,0.0000493628,0.00001163353,0.0004733283,0.998518,0.00001844279,0.0005849876,0.00000194444],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893112,0.0005170717,0.006592207,0.0001237002,0.00004169047,0.0000384082,0.0002268269,0.0001341506,0.003014752],"genre_scores_gemma":[0.99473,0.0002651194,0.00305756,0.00002004866,0.00000454477,0.00001072705,0.0001475045,0.00002101418,0.001743537],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001685382,"threshold_uncertainty_score":0.003697753,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02095145498720946,"score_gpt":0.236755201318041,"score_spread":0.2158037463308315,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}