{"id":"W2609852383","doi":"10.3390/inorganics5020030","title":"Backbone-Substituted β-Ketoimines and Ketoiminate Clusters: Transoid Li2O2 Squares and D2-Symmetric Li4O4 Cubanes. Synthesis, Crystallography and DFT Calculations","year":2017,"lang":"en","type":"article","venue":"Inorganics","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; University of Lethbridge","keywords":"Chemistry; Tetrahydrofuran; Crystallography; Aryl; Ligand (biochemistry); Ring (chemistry); Crystal structure; Deprotonation; Stereochemistry; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001430649,0.0004251944,0.0004941789,0.0002716869,0.000325722,0.0006017588,0.0008770457,0.0005275601,0.004439312],"category_scores_gemma":[0.0002967564,0.0002774616,0.0002115496,0.0003346118,0.0002559347,0.0003581771,0.0003535202,0.0004673316,0.0004303513],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009175268,"about_ca_system_score_gemma":0.000554295,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00970827,"about_ca_topic_score_gemma":0.01282048,"domain_scores_codex":[0.9999486,0.000007343666,0.000002391294,0.00001009397,0.00001538257,0.00001616623],"domain_scores_gemma":[0.9999037,0.00002653886,0.00001412509,0.000008425088,0.00002064215,0.0000265365],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003405108,0.0005487035,0.01096311,0.006368439,0.0003381922,0.001721266,0.0007670533,0.6720238,0.2134768,0.04733458,0.01974093,0.02331195],"study_design_scores_gemma":[0.0008535111,0.000940748,0.005122195,0.0001121853,0.0001044333,0.0002016647,0.0009027309,0.9228134,0.04929008,0.004668553,0.01490829,0.00008223709],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870079,0.0006373443,0.00110732,0.0002034894,0.00003357304,0.00003391716,0.001360266,0.0001262412,0.009490006],"genre_scores_gemma":[0.9883309,0.0005255379,0.005675565,0.00006733797,0.00001696785,0.0001293464,0.002879717,0.0001330977,0.002241478],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00970827,"threshold_uncertainty_score":0.01930356,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01540060460927216,"score_gpt":0.237663136100308,"score_spread":0.2222625314910359,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}