{"id":"W2610261413","doi":"10.1149/ma2017-01/14/896","title":"Redox Properties of Transition-Metal/Organic Chromophore Arrays: Interplay Between Metal- and Chromophore-Centered Electron-Transfer Processes","year":2017,"lang":"en","type":"article","venue":"ECS Meeting Abstracts","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Chromophore; Transition metal; Ferrocene; Redox; Time-dependent density functional theory; Electron transfer; Photochemistry; Metal; Electrochemistry; Chemistry; Materials science; Crystallography; Physical chemistry; Computational chemistry; Inorganic chemistry; Density functional theory; Organic chemistry; Catalysis; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001135206,0.0001261471,0.0001437407,0.00009897872,0.00008164084,0.0002951768,0.0002185079,0.0001802754,0.001295611],"category_scores_gemma":[0.0002145475,0.00009134327,0.00006413391,0.0001067504,0.0001549196,0.0002482261,0.0001125488,0.0001977976,0.000154253],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000213429,"about_ca_system_score_gemma":0.00005851415,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003405417,"about_ca_topic_score_gemma":0.0004672254,"domain_scores_codex":[0.9999403,0.000006963694,0.000003542293,0.00001903863,0.00001764343,0.00001247349],"domain_scores_gemma":[0.9999404,0.00002822947,0.00001035058,0.000004741958,0.000008817487,0.000007446925],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007599262,0.00001436321,0.0002826618,0.00004398577,0.000008845964,0.00003026103,0.00001762404,0.000511535,0.9962605,0.0002399519,0.00003930788,0.002475119],"study_design_scores_gemma":[0.000008144532,0.00008134166,0.001528833,0.000002259846,0.00001052474,0.00005277237,0.00001920351,0.002899491,0.994904,0.00006653351,0.0004230384,0.000003832359],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976932,0.0003342263,0.001000763,0.00003053562,0.000003386062,0.000003973773,0.00007552897,0.00002198901,0.0008364555],"genre_scores_gemma":[0.9988451,0.0001794947,0.0005867087,0.000009879884,0.000001482793,0.000002911136,0.00004890736,0.000005242409,0.0003202568],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001295611,"threshold_uncertainty_score":0.004334211,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01971624083657362,"score_gpt":0.2522252856703824,"score_spread":0.2325090448338088,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}