{"id":"W2611524477","doi":"10.1002/chem.201702008","title":"Amphoteric Borylketenimines: Versatile Intermediates in the Synthesis of Borylated Heterocycles","year":2017,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Regioselectivity; Nucleophile; Combinatorial chemistry; Sulfonyl; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005289149,0.0001557267,0.0001996073,0.00001978131,0.0001773227,0.0001300882,0.0009801238,0.00004952526,0.00009228279],"category_scores_gemma":[0.0006579582,0.0001086883,0.0002186283,0.0000381538,0.0002096244,0.000008310931,0.0001520217,0.0001799381,0.000005594166],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001207036,"about_ca_system_score_gemma":0.00002218369,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005201747,"about_ca_topic_score_gemma":0.000001808973,"domain_scores_codex":[0.9989501,0.0001278977,0.0003580826,0.0002086638,0.0001505807,0.0002046879],"domain_scores_gemma":[0.998881,0.00004057849,0.0003830586,0.0005642262,0.00005459705,0.00007657171],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005050677,0.0000644091,0.004331961,0.00002705902,0.00006188121,0.00004950494,0.00008131549,0.000004229237,0.9884539,1.383034e-7,0.0005806481,0.006294414],"study_design_scores_gemma":[0.0004310391,0.00003545669,0.02305283,0.000129585,0.00006362849,0.0001278803,0.0004194261,0.0001188984,0.9706643,0.00001160779,0.004749635,0.0001956739],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964924,0.0002407976,0.00002642509,0.0002096212,0.00003266563,0.00002683662,0.00001184031,0.000003251363,0.00295611],"genre_scores_gemma":[0.9991587,0.0002971664,0.00008302968,0.00004842636,0.0002973799,0.000002660605,0.00001083769,0.00001995691,0.00008179754],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01872087,"threshold_uncertainty_score":0.443218,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0106353737445669,"score_gpt":0.2316401634522032,"score_spread":0.2210047897076363,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}