{"id":"W2611771129","doi":"10.1039/c7ob00892a","title":"A room temperature cyanation of (hetero)aromatic chlorides by an air stable nickel(<scp>ii</scp>) XantPhos precatalyst and Zn(CN)<sub>2</sub>","year":2017,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Vancouver Biotech (Canada); University of British Columbia","funders":"","keywords":"Xantphos; Chemistry; Cyanation; Nickel; Aryl; Cyanide; Polymer chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001614354,0.0004246963,0.0002872695,0.0001419976,0.0002682096,0.0002168885,0.0004072277,0.0002952644,0.0008565101],"category_scores_gemma":[0.0001625891,0.0001768356,0.0001647972,0.0001639927,0.0002893859,0.0003307636,0.0004486444,0.0004623629,0.0003425443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000379708,"about_ca_system_score_gemma":0.0004782143,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001170894,"about_ca_topic_score_gemma":0.003358999,"domain_scores_codex":[0.9998549,0.00001442656,0.00000961754,0.00003998772,0.00004615693,0.00003485291],"domain_scores_gemma":[0.9999157,0.000008070352,0.00002864169,0.00001337396,0.00001710908,0.00001708251],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005007588,0.00001685394,0.0001931412,0.0001346163,0.00001527048,0.0001332479,0.0000502829,0.0002067614,0.9934686,0.0005156659,0.0001066883,0.005108753],"study_design_scores_gemma":[0.000003659567,0.00007936892,0.0003660431,0.000003117276,0.000006226415,0.0002214244,0.000008097267,0.0001968723,0.9970573,0.00002349964,0.002029544,0.000004839199],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9390644,0.005432571,0.04214462,0.0001951747,0.0001296535,0.0001988835,0.0004215288,0.0004673339,0.01194579],"genre_scores_gemma":[0.9710361,0.002487148,0.01960619,0.00005008986,0.00001391903,0.000060115,0.0002846585,0.00004957244,0.006412316],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001170894,"threshold_uncertainty_score":0.002865314,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004925734463214258,"score_gpt":0.2210929389163705,"score_spread":0.2161672044531563,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}