{"id":"W2612800648","doi":"10.1039/c7an00330g","title":"High pH instability of quaternary ammonium surfactant coatings in capillary electrophoresis","year":2017,"lang":"en","type":"article","venue":"The Analyst","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Hospital Edmonton; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"Cationic polymerization; Chemistry; Pulmonary surfactant; Ammonium; Amine gas treating; Bromide; Yield (engineering); Inorganic chemistry; Decomposition; Electrophoresis; Chemical engineering; Chromatography; Organic chemistry; Materials science; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006195395,0.0003237184,0.0001346526,0.0002476167,0.0002085173,0.0005594389,0.0002303786,0.0003840991,0.0004598325],"category_scores_gemma":[0.0008858104,0.0001560118,0.0001506724,0.0001435329,0.0003278842,0.0003372311,0.0003018288,0.0003736889,0.0002241525],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003683991,"about_ca_system_score_gemma":0.0002870625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008461197,"about_ca_topic_score_gemma":0.001313868,"domain_scores_codex":[0.9996214,0.00006165645,0.00002489189,0.00005761446,0.0001710742,0.00006330753],"domain_scores_gemma":[0.9994554,0.0001790974,0.0001191294,0.00002887917,0.0001712739,0.00004613901],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001878567,0.000004838326,0.0003308274,0.00002673047,0.000004817331,0.0000510775,0.00002767668,0.00005936745,0.9972947,0.00009568851,0.00003292613,0.002052485],"study_design_scores_gemma":[0.000002050011,0.00007038417,0.001458543,0.000007173279,0.00000689735,0.0002252828,0.00001606661,0.0007888207,0.9965683,0.00005018908,0.0008020402,0.00000424262],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9802887,0.003622775,0.01331402,0.0001524726,0.00003987504,0.0000340091,0.00007818591,0.0001108408,0.002359157],"genre_scores_gemma":[0.9928652,0.0008850018,0.004542062,0.00008410752,0.00001007924,0.00001610973,0.00009409872,0.0000199948,0.00148337],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008461197,"threshold_uncertainty_score":0.003276527,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008564517532517706,"score_gpt":0.2158496147435647,"score_spread":0.207285097211047,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}