{"id":"W2614248001","doi":"10.1002/anie.201702497","title":"Structural Dynamics upon Photoexcitation in a Spin Crossover Crystal Probed with Femtosecond Electron Diffraction","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Deutsche Forschungsgemeinschaft; Max-Planck-Gesellschaft; Agence Nationale de la Recherche; Association Nationale de la Recherche et de la Technologie; Natural Sciences and Engineering Research Council of Canada; European Commission","keywords":"Photoexcitation; Femtosecond; Spin crossover; Diffraction; Electron; Electron diffraction; Dynamics (music); Crystal (programming language); Materials science; Spin (aerodynamics); Molecular physics; Chemical physics; Atomic physics; Condensed matter physics; Physics; Optics; Laser; Excited state; Quantum mechanics; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002130569,0.0001845496,0.0001551549,0.0001453473,0.0002836002,0.0005772146,0.0003911434,0.0000983986,0.001583367],"category_scores_gemma":[0.0002164045,0.000176442,0.00004216433,0.00006420657,0.0001132691,0.001764304,0.00007224624,0.000180642,0.00003172685],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005208454,"about_ca_system_score_gemma":0.00006192841,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004936717,"about_ca_topic_score_gemma":0.002921393,"domain_scores_codex":[0.998522,0.00002550276,0.0002979318,0.0003949418,0.0005085732,0.000251067],"domain_scores_gemma":[0.9988942,0.00005839172,0.0004471355,0.000276926,0.000273049,0.00005031826],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005085077,0.00007890055,0.003378197,0.00003698192,0.00001515057,0.00001445468,0.0002659994,0.00019311,0.9915093,0.002099634,0.0008922646,0.00100757],"study_design_scores_gemma":[0.001688685,0.0001197968,0.1446953,0.00007657089,0.000009784866,0.00003575021,0.00008261022,0.006514404,0.8418075,0.004127342,0.0005757959,0.0002663887],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9888155,0.00001049157,0.00231969,0.001182453,0.001433912,0.00028649,0.0001239909,0.00006455849,0.005762867],"genre_scores_gemma":[0.9972048,0.000006613024,0.0006763801,0.00008197755,0.0006489975,0.0001012696,0.0005859419,0.00002120185,0.0006727673],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1497017,"threshold_uncertainty_score":0.9993293,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01380812758626706,"score_gpt":0.284718313400677,"score_spread":0.27091018581441,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}