{"id":"W2616672232","doi":"10.1021/acs.inorgchem.7b01140","title":"Direct Synthesis of an Unprecedented Stable Radical of Nickel(II) 3,5-Bis(dimedonyl)azadiisoindomethene with Strong and Narrow Near-Infrared Absorption at λ ∼ 1000 nm","year":2017,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; University of Manitoba","keywords":"Chemistry; Nickel; Infrared; Absorption (acoustics); Photochemistry; Infrared spectroscopy; Absorption spectroscopy; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001578314,0.0003059612,0.0002220703,0.0001498563,0.0001931312,0.0002267225,0.0003902054,0.0002891239,0.001335795],"category_scores_gemma":[0.000129228,0.0001502595,0.0001672604,0.0001368119,0.0001399515,0.0002733122,0.0003114616,0.0003342964,0.0003530907],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002824105,"about_ca_system_score_gemma":0.0001733976,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002264113,"about_ca_topic_score_gemma":0.0006758699,"domain_scores_codex":[0.9999136,0.000009587479,0.000007106447,0.00002724185,0.00001998961,0.00002240503],"domain_scores_gemma":[0.9999448,0.000005605606,0.00001482314,0.000008949023,0.000008218266,0.00001764353],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002565743,0.00001967781,0.00004543326,0.00007621965,0.000004860108,0.00005236547,0.00004267083,0.00008348147,0.9971398,0.0004346143,0.00004978873,0.002025467],"study_design_scores_gemma":[0.00003073604,0.0003270195,0.0004425943,0.000003629056,0.00000917636,0.0001463424,0.00001396961,0.0003398262,0.9939995,0.0000491993,0.004628305,0.000009926706],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9867937,0.0007776372,0.008401726,0.00009450235,0.00003972269,0.00009405836,0.0002704007,0.0001221479,0.003405967],"genre_scores_gemma":[0.9900839,0.0004075371,0.006251358,0.00002360918,0.000009792439,0.00004363239,0.0002838073,0.000019715,0.00287655],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001335795,"threshold_uncertainty_score":0.004468679,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0089780204298824,"score_gpt":0.2287949875725031,"score_spread":0.2198169671426207,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}