{"id":"W2616672232","doi":"10.1021/acs.inorgchem.7b01140","title":"Direct Synthesis of an Unprecedented Stable Radical of Nickel(II) 3,5-Bis(dimedonyl)azadiisoindomethene with Strong and Narrow Near-Infrared Absorption at λ ∼ 1000 nm","year":2017,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; University of Manitoba","keywords":"Chemistry; Nickel; Infrared; Absorption (acoustics); Photochemistry; Infrared spectroscopy; Absorption spectroscopy; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004668117,0.0002507186,0.0005732427,0.00002553273,0.0003845262,0.0001291874,0.0006015169,0.0001844481,0.001902871],"category_scores_gemma":[0.0002807753,0.0002112785,0.00005110659,0.00006524102,0.0007882033,0.0004191907,0.0002889158,0.00008159289,0.00001129347],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008448784,"about_ca_system_score_gemma":0.0001689814,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003428384,"about_ca_topic_score_gemma":0.0000361468,"domain_scores_codex":[0.9982263,0.00006016996,0.0004743563,0.0004723179,0.0004095909,0.0003572498],"domain_scores_gemma":[0.9980333,0.00008891726,0.000598484,0.0009815163,0.0001226453,0.0001750936],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000409931,0.0001558217,0.004737986,0.0003252769,0.00002680224,0.000006757526,0.0002431379,0.000003969291,0.9938767,0.000003934091,0.00009956287,0.0001101214],"study_design_scores_gemma":[0.0009181112,0.00009347459,0.004819718,0.0002179427,0.0000782845,0.00003346816,0.0001026179,0.00004834848,0.9933401,0.000009665016,0.0001051313,0.0002331037],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979904,0.0001086939,0.000004977287,0.0000582866,0.00009547525,0.000167506,0.0001179167,0.00005157263,0.001405156],"genre_scores_gemma":[0.9982123,0.00002762974,0.0004692129,0.000007105218,0.00008229479,0.00001465076,0.00002276705,0.00003488075,0.00112921],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001891578,"threshold_uncertainty_score":0.9990095,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0089780204298824,"score_gpt":0.2287949875725031,"score_spread":0.2198169671426207,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}