{"id":"W2618434403","doi":"10.1021/acs.organomet.7b00235","title":"Thermal Ring-Opening Polymerization of Planar-Chiral Sila[1]ferrocenophanes","year":2017,"lang":"en","type":"article","venue":"Organometallics","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Enantiopure drug; Monomer; Polymerization; Ring-opening polymerization; Differential scanning calorimetry; Crystallography; Ring (chemistry); Polymer; Polymer chemistry; Crystal structure; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002144703,0.0001479924,0.0002613384,0.00007058692,0.0004802796,0.0001754281,0.0006860916,0.000066113,0.00107888],"category_scores_gemma":[0.0001223419,0.0001308401,0.00006667951,0.00009775652,0.0001908678,0.0003739551,0.0001203296,0.00005580874,0.0002081802],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001390381,"about_ca_system_score_gemma":0.00004044523,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006694425,"about_ca_topic_score_gemma":0.000007711216,"domain_scores_codex":[0.9989617,0.00002577794,0.0002925342,0.0002582129,0.0002118508,0.0002498661],"domain_scores_gemma":[0.9987432,0.00004343809,0.0004047249,0.0006855661,0.00004436048,0.00007869466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007774287,0.0000517081,0.001769063,0.00001476801,0.00001194545,0.000001001492,0.0001394554,0.0000169405,0.9907638,0.005776715,0.000007340909,0.001439531],"study_design_scores_gemma":[0.0001738715,0.00002547466,0.03661349,0.00002149771,0.00003801088,0.000002756391,0.00004081761,0.0001340063,0.9616358,0.0003065697,0.0008336642,0.0001740561],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9869249,0.0001666445,0.0005668303,0.0002449729,0.0001564487,0.0001210202,0.000048473,0.0000529131,0.01171773],"genre_scores_gemma":[0.9972417,0.00002702895,0.00139655,0.00003727387,0.0001065958,0.00001394073,0.00001417583,0.00002777144,0.001135007],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03484443,"threshold_uncertainty_score":0.9998342,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02185107012841174,"score_gpt":0.2551917272073319,"score_spread":0.2333406570789202,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}