{"id":"W2618536580","doi":"10.1021/acs.joc.7b00687","title":"Hydrogen Atom Transfer (HAT) Processes Promoted by the Quinolinimide-<i>N</i>-oxyl Radical. A Kinetic and Theoretical Study","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Okanagan University College; University of British Columbia, Okanagan Campus; University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; University of British Columbia; Ministero dell’Istruzione, dell’Università e della Ricerca; Canada Foundation for Innovation","keywords":"Hydrogen atom; Kinetic energy; Hydrogen; Chemistry; Atom (system on chip); Thermodynamics; Photochemistry; Physics; Organic chemistry; Classical mechanics; Group (periodic table); Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007717755,0.0003928307,0.0004826611,0.00001163994,0.0007969161,0.0002140647,0.001869472,0.0002074195,0.004861407],"category_scores_gemma":[0.001120457,0.0002290827,0.0001227978,0.0001390712,0.001499972,0.0001369591,0.0002627634,0.001211986,0.000009894585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001125782,"about_ca_system_score_gemma":0.0003825292,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008876208,"about_ca_topic_score_gemma":0.000004808113,"domain_scores_codex":[0.9978201,0.00006540665,0.0007383216,0.0003143675,0.0006636576,0.0003981615],"domain_scores_gemma":[0.997177,0.0005013941,0.0005473075,0.001231555,0.0002810474,0.0002617167],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001560511,0.0005000629,0.001427278,0.0002150189,0.0003630498,0.00003092348,0.00117783,3.775768e-7,0.9952174,0.000008745647,0.0004920816,0.0004112092],"study_design_scores_gemma":[0.001891753,0.00006628029,0.0003143809,0.0001320353,0.000652493,0.002281936,0.002309678,0.00001482037,0.9898936,0.000377158,0.00178826,0.0002776592],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929928,0.001041731,0.00005763768,0.002943346,0.00003746196,0.0001678453,0.00003542385,0.0000387483,0.002685069],"genre_scores_gemma":[0.998367,0.0003318156,0.00001731179,0.000051206,0.0004380951,0.000007547186,0.000003669251,0.00007119386,0.0007121523],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005374271,"threshold_uncertainty_score":0.9960483,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01027915357003289,"score_gpt":0.2451774025589887,"score_spread":0.2348982489889558,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}