{"id":"W2618735203","doi":"10.1021/jacs.7b04067","title":"Stable Chloro- and Bromoxenate Cage Anions; [X<sub>3</sub>(XeO<sub>3</sub>)<sub>3</sub>]<sup>3–</sup> and [X<sub>4</sub>(XeO<sub>3</sub>)<sub>4</sub>]<sup>4–</sup> (X = Cl or Br)","year":2017,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Lone pair; Halogen; Crystallography; Isostructural; Bromine; Valence (chemistry); Xenon; Bond length; Krypton; Crystal structure; Chemical bond; Molecule; Alkyl; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.003490118,0.00452069,0.005976569,0.0005679245,0.004904828,0.002512474,0.005868314,0.003234429,0.00009870875],"category_scores_gemma":[0.001749059,0.003813298,0.004489668,0.002601238,0.00572036,0.002742356,0.004327019,0.01055716,0.0002692773],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003265315,"about_ca_system_score_gemma":0.002193984,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002519471,"about_ca_topic_score_gemma":0.0000763422,"domain_scores_codex":[0.9784128,0.0008499032,0.005713995,0.004319758,0.004701568,0.006001963],"domain_scores_gemma":[0.9796351,0.002035337,0.007584563,0.005152754,0.00191138,0.003680915],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001905347,0.001473685,0.001485832,0.0009577139,0.003160542,0.0006389422,0.00274318,0.000804721,0.9252044,0.00005764292,0.03948728,0.0220807],"study_design_scores_gemma":[0.008522729,0.0008621666,0.001256631,0.001841379,0.002645691,0.004620033,0.003376848,0.008176927,0.9591522,0.001049585,0.003941088,0.004554689],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874395,0.003014849,0.0003318644,0.004144433,0.001296123,0.001435934,0.0008558692,0.0006968473,0.000784648],"genre_scores_gemma":[0.9685224,0.0217304,0.0007296976,0.00281495,0.00450734,0.0001675334,0.000243131,0.001160764,0.0001238187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03554619,"threshold_uncertainty_score":0.9995104,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009294212163460347,"score_gpt":0.2224071255507508,"score_spread":0.2131129133872904,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}