{"id":"W2620283829","doi":"10.1021/acs.inorgchem.7b00707","title":"In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1: Effect of Liquid Additives on the Milling Reactivity","year":2017,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":140,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Zaklade Adris; Natural Sciences and Engineering Research Council of Canada; Hrvatska Zaklada za Znanost; McGill University","keywords":"Mechanosynthesis; Chemistry; Metal-organic framework; Synchrotron; Mechanochemistry; In situ; Porosity; Reactivity (psychology); Chemical engineering; Metal; Nanotechnology; Organic chemistry; Adsorption; Ball mill; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007537681,0.000344381,0.0006234625,0.0000195574,0.0003511967,0.00002960247,0.002253321,0.0004499844,0.0009667456],"category_scores_gemma":[0.006734834,0.0001954316,0.0004247471,0.0002779413,0.0005166029,0.00007887943,0.000568039,0.001095601,0.000005070926],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000105403,"about_ca_system_score_gemma":0.0001169606,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005603493,"about_ca_topic_score_gemma":0.000006860623,"domain_scores_codex":[0.9979368,0.0001391867,0.0006160301,0.0004361212,0.0005531959,0.0003186403],"domain_scores_gemma":[0.9923362,0.003286901,0.001186046,0.003047544,0.00008756758,0.00005571533],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006965875,0.0001515571,0.002410607,0.0003332501,0.0001361403,5.879739e-7,0.0002697588,0.000003323353,0.9960154,0.0001806282,0.00001801977,0.0004110931],"study_design_scores_gemma":[0.0001729254,0.00001811955,0.002507252,0.001315655,0.0001606835,0.000004389665,0.0003071591,0.00001051036,0.9946542,0.0005966749,0.00007852326,0.0001738707],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959615,0.0001949139,0.00002977504,0.0008838635,0.0001440038,0.0002094941,0.00006569784,0.00001709261,0.002493616],"genre_scores_gemma":[0.9992467,0.00009251953,0.00008105362,0.00001463606,0.0002483391,0.00005262356,0.000001292032,0.00005293833,0.0002099003],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005981066,"threshold_uncertainty_score":0.9999465,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01611275219546735,"score_gpt":0.2526999841290402,"score_spread":0.2365872319335729,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}