{"id":"W2624235896","doi":"10.1021/acs.langmuir.7b00518","title":"Phosphorus Pentachloride Initiated Functionalization of Silicon Nanocrystals","year":2017,"lang":"en","type":"article","venue":"Langmuir","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphorus pentachloride; Surface modification; Quantum yield; Chemistry; Silicon; Photoluminescence; Alkyl; Nanocrystal; Photochemistry; Polymer chemistry; Nanotechnology; Materials science; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001175197,0.0002388489,0.0001295566,0.0001300675,0.0001104025,0.0001924839,0.0001803238,0.0002010231,0.001035425],"category_scores_gemma":[0.0001670789,0.0001205259,0.0002123202,0.00008850018,0.0001723091,0.0001468765,0.000162901,0.0002639234,0.0002472501],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004104058,"about_ca_system_score_gemma":0.0002569239,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001445133,"about_ca_topic_score_gemma":0.002195782,"domain_scores_codex":[0.9998797,0.00001108206,0.000008097715,0.00002322608,0.00004066352,0.00003720404],"domain_scores_gemma":[0.9999157,0.0000250448,0.00002088128,0.000009668061,0.00001764604,0.00001102583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002083959,0.000005196673,0.00004215264,0.00001886019,0.000002171819,0.00003172238,0.00001373493,0.0001051492,0.9991401,0.00007314306,0.00001658045,0.0005304067],"study_design_scores_gemma":[0.000002672517,0.00002936506,0.0002544478,7.277048e-7,0.000001233946,0.00001500111,0.000005077392,0.0003061325,0.9990727,0.000007165271,0.0003041275,0.000001445666],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949551,0.0003089857,0.001988232,0.00004577502,0.00001684057,0.0000305319,0.0001489763,0.00004035207,0.002465172],"genre_scores_gemma":[0.995719,0.0002669881,0.002041277,0.00002426307,0.000004591222,0.00002221717,0.000194648,0.00001738905,0.001709651],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001445133,"threshold_uncertainty_score":0.003463805,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03010396825743842,"score_gpt":0.279071841836471,"score_spread":0.2489678735790326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}