{"id":"W2625391045","doi":"10.1139/cjc-2017-0209","title":"Accelerated hydrolysis of boronic acid in a modified poly(amidoamine) dendrimer: identification of a factor leading to the production of an impurity in boronic acid containing poly(amidoamine) dendrimers","year":2017,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Dendrimer; Boronic acid; Chemistry; Poly(amidoamine); Amidoamine; Hydrolysis; Proton NMR; Organic chemistry; Carbon-13 NMR; Combinatorial chemistry; Polymer chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001000202,0.0002383617,0.0006750032,0.0003290745,0.0001639076,0.0001053343,0.001103003,0.0001704251,0.0001296595],"category_scores_gemma":[0.0006349371,0.0002204302,0.0001471799,0.0003267894,0.0003271792,0.0006360681,0.00004519161,0.000339126,0.000002141566],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003949768,"about_ca_system_score_gemma":0.001515577,"about_ca_topic_candidate":true,"about_ca_topic_consensus":true,"about_ca_topic_score_codex":0.01403186,"about_ca_topic_score_gemma":0.02730586,"domain_scores_codex":[0.9974313,0.0001019744,0.001250236,0.0003395236,0.0003722841,0.0005047158],"domain_scores_gemma":[0.9969415,0.00003700228,0.001618829,0.0007622709,0.0002758336,0.0003645828],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001520358,0.00005233334,0.006747053,0.0000951395,0.00004375575,0.00002197626,0.002604721,0.0002128393,0.9874131,0.000007007316,0.00001472054,0.002635303],"study_design_scores_gemma":[0.0006468993,0.00008947447,0.03205885,0.0002556285,0.00005142267,0.00005437264,0.001131683,0.0001622011,0.9653232,0.00001425406,0.00002516203,0.000186847],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957378,0.003031137,0.00003045157,0.0003083713,0.000416329,0.0001804468,0.00007838092,0.000004356869,0.0002127448],"genre_scores_gemma":[0.9996138,0.00002804758,0.0000866671,0.00001586667,0.0001175442,0.000006788224,0.000008439587,0.00002566216,0.00009721866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02531179,"threshold_uncertainty_score":0.9925338,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02627401900808447,"score_gpt":0.2727149941625045,"score_spread":0.24644097515442,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}