{"id":"W2625639923","doi":"10.1016/j.jct.2017.05.033","title":"Standard partial molar heat capacities and volumes of aqueous N-methylpiperidine and N-methylpiperidinium chloride from 283 K to 393 K","year":2017,"lang":"en","type":"article","venue":"The Journal of Chemical Thermodynamics","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"Agence Nationale de la Recherche","keywords":"Chemistry; Heat capacity; Partial molar property; Apparent molar property; Thermodynamics; Dilution; Calorimeter (particle physics); Analytical Chemistry (journal); Molar; Chloride; Aqueous solution; Physical chemistry; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005177588,0.0006007176,0.0003506674,0.0008711469,0.0006070906,0.0003239747,0.001441501,0.00055752,0.004423434],"category_scores_gemma":[0.001335514,0.0003243647,0.0002966959,0.001186009,0.0006595731,0.0009763109,0.0004473109,0.001136552,0.0009120704],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007550674,"about_ca_system_score_gemma":0.0005469442,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00197506,"about_ca_topic_score_gemma":0.002141409,"domain_scores_codex":[0.999435,0.00005061403,0.00004228569,0.0001450615,0.0002351291,0.00009178723],"domain_scores_gemma":[0.9995453,0.0001468677,0.00005455213,0.00006595761,0.0001647126,0.00002267302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007564722,0.00005218416,0.002721909,0.0003395499,0.00004442569,0.0001363277,0.0002715107,0.004510501,0.9742967,0.001663785,0.001401733,0.01380486],"study_design_scores_gemma":[0.00001256175,0.0001272366,0.001946183,0.000007043481,0.00001137927,0.00006756833,0.00004278524,0.002256913,0.9928854,0.0002988733,0.002323922,0.00002023905],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9685449,0.001393581,0.01372404,0.0002641726,0.00008885154,0.00007397491,0.006869072,0.001090815,0.007950584],"genre_scores_gemma":[0.9854499,0.001012899,0.004636752,0.00005782187,0.00001531249,0.0001754216,0.005368751,0.000136441,0.003146845],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004423434,"threshold_uncertainty_score":0.01479787,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01032737591055345,"score_gpt":0.2306371985061902,"score_spread":0.2203098225956367,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}