{"id":"W2625735993","doi":"10.1021/jacs.7b05574","title":"Nickel-Catalyzed C–H Silylation of Arenes with Vinylsilanes: Rapid and Reversible β-Si Elimination","year":2017,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Silylation; Reductive elimination; Catalysis; Alkene; Ethylene; Medicinal chemistry; Isopropyl; Imidazole; Organic chemistry; Photochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003488426,0.0001112406,0.0002974828,0.00001519349,0.0001586006,0.00003922276,0.0003497132,0.00005327572,0.00008754448],"category_scores_gemma":[0.0005720984,0.0000746673,0.000213384,0.0001107809,0.0006243573,0.000177176,0.0001103698,0.0001951437,4.747542e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001030277,"about_ca_system_score_gemma":0.00009185652,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004188254,"about_ca_topic_score_gemma":0.000001176468,"domain_scores_codex":[0.9990128,0.00002113033,0.0003340879,0.0001292654,0.0003947035,0.0001080589],"domain_scores_gemma":[0.9971795,0.0002315827,0.001858754,0.0003754828,0.0002906501,0.00006401465],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000131892,0.00005192836,0.02130311,0.00007503947,0.0001396474,5.134027e-7,0.0002740586,0.00002937996,0.9722061,0.0000240855,0.001401082,0.004363182],"study_design_scores_gemma":[0.00114889,0.00003708853,0.02666844,0.0001626919,0.0002332851,0.0001044234,0.001059176,0.0006684588,0.9680268,0.0002547805,0.001474744,0.000161249],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968681,0.00009576294,0.001163019,0.00135256,0.00005651383,0.00003237616,0.0000097307,0.000006844562,0.000415059],"genre_scores_gemma":[0.9914905,0.0001423294,0.007800617,0.00009130815,0.000195497,0.000001331837,0.000007841234,0.00001393693,0.0002565766],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006637597,"threshold_uncertainty_score":0.3044844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0176445699846885,"score_gpt":0.2786934250779034,"score_spread":0.2610488550932149,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}