{"id":"W2712299011","doi":"10.1016/j.ijms.2017.06.006","title":"Dual-electrospray synthesis: A method of studying unique coordination complexes in the gas phase","year":2017,"lang":"en","type":"article","venue":"International Journal of Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Dissociation (chemistry); Ruthenium; Ligand (biochemistry); Ion; Electrospray; Bipyridine; Collision-induced dissociation; Mass spectrometry; Physical chemistry; Crystallography; Crystal structure; Tandem mass spectrometry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002845481,0.0004472886,0.0002368431,0.0003476252,0.0003536832,0.000405752,0.0005927218,0.0004293754,0.002127969],"category_scores_gemma":[0.0003612677,0.0002419923,0.0001436194,0.0001966467,0.0003388365,0.0006332335,0.0004045588,0.0005487454,0.0004662621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003274326,"about_ca_system_score_gemma":0.0002736648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003786782,"about_ca_topic_score_gemma":0.0004917795,"domain_scores_codex":[0.9997683,0.0000250087,0.000008391457,0.00009804794,0.0000790381,0.00002131215],"domain_scores_gemma":[0.9998616,0.00003101236,0.00003731541,0.00002065547,0.00002950476,0.00001987335],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006663,0.00000934827,0.00008998684,0.00003272472,0.00000449189,0.00003032236,0.00002510125,0.00003218328,0.9961986,0.0004649339,0.0001754183,0.00287022],"study_design_scores_gemma":[0.00002192875,0.00008296687,0.0003684527,0.000002928287,0.000005080617,0.0001853686,0.00001494306,0.0009407765,0.9941397,0.0001860474,0.004044424,0.000007484572],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.8331208,0.002972312,0.1458729,0.000742277,0.0001967695,0.000215609,0.0009891869,0.0008607258,0.01502942],"genre_scores_gemma":[0.9324638,0.001371086,0.05700237,0.0002057858,0.00004889281,0.0001028663,0.0004370569,0.0001833908,0.008184743],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.002127969,"threshold_uncertainty_score":0.007118762,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03105144226374274,"score_gpt":0.3632963367256384,"score_spread":0.3322448944618957,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}