{"id":"W2722297201","doi":"10.1021/acs.organomet.7b00373","title":"Exploring the Influence of Phosphine Ligation on the Gold-Catalyzed Hydrohydrazination of Terminal Alkynes at Room Temperature","year":2017,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts; Dalhousie University","keywords":"Chemistry; Phosphine; Catalysis; Aryl; Hydrate; Hydrazine (antidepressant); Silylation; Medicinal chemistry; Ether; Combinatorial chemistry; Activator (genetics); Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000225136,0.0001737572,0.0002155709,0.00004797563,0.0004248015,0.0000660134,0.0006996188,0.00007495546,0.0001383495],"category_scores_gemma":[0.0007224507,0.000109497,0.0001140383,0.000171736,0.0002461484,0.0004258263,0.0002079325,0.0002239662,0.00003273254],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001121091,"about_ca_system_score_gemma":0.00004639108,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001084616,"about_ca_topic_score_gemma":0.0000505771,"domain_scores_codex":[0.9989026,0.00001119385,0.0003342546,0.0002189323,0.0003767657,0.0001563171],"domain_scores_gemma":[0.9976732,0.000246355,0.0005774337,0.001310724,0.0001539768,0.00003833995],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002583313,0.00007750309,0.0008888461,0.00006947673,0.0000727748,0.00000219499,0.0005975887,0.0001852001,0.9953384,0.001463893,0.00003492278,0.001243375],"study_design_scores_gemma":[0.0002250933,0.00001378887,0.03452384,0.000110119,0.00008906903,0.00001825023,0.0001664548,0.0001250055,0.9632485,0.0002166004,0.001136316,0.0001269524],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961654,0.00004343862,0.000001533348,0.001316455,0.00007819432,0.0001189525,0.00003885934,0.00002451361,0.002212653],"genre_scores_gemma":[0.9980902,0.0001206644,0.00001652438,0.0000177045,0.00009969946,0.0000392546,0.00004951969,0.00002676502,0.001539637],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.033635,"threshold_uncertainty_score":0.4465158,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03565044050328737,"score_gpt":0.2463445831149702,"score_spread":0.2106941426116828,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}