{"id":"W2725011362","doi":"10.1016/j.ijms.2017.06.008","title":"Ligation kinetics as a probe for relativistic effects in ion chemistry: Gas-phase ligation of late atomic transition metal cations with OCS and CH3Cl at room temperature","year":2017,"lang":"en","type":"article","venue":"International Journal of Mass Spectrometry","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Metal; Relativistic quantum chemistry; Analytical Chemistry (journal); Kinetics; Ion; Inorganic chemistry; Atomic physics; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006673841,0.0003299054,0.0002328187,0.000199357,0.0004321838,0.0005125485,0.0007307181,0.0004909765,0.003040895],"category_scores_gemma":[0.0009549218,0.0002689868,0.0002281222,0.0003056717,0.0009418736,0.0007142652,0.000352084,0.0009125768,0.0004868738],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005727436,"about_ca_system_score_gemma":0.0003782448,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002165493,"about_ca_topic_score_gemma":0.001682309,"domain_scores_codex":[0.999657,0.00006669523,0.00001478546,0.00008422219,0.00006810504,0.0001090769],"domain_scores_gemma":[0.9995779,0.000171817,0.0001028519,0.00005519024,0.00006130433,0.00003096736],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001411718,0.00007102004,0.0008108968,0.0000616065,0.00001836355,0.00006500077,0.0002586784,0.0003483496,0.9940051,0.0004594056,0.0002561455,0.002233655],"study_design_scores_gemma":[0.00002555998,0.0002941082,0.001141809,0.000002430734,0.00000810887,0.00003682544,0.00006949356,0.001395774,0.9962282,0.00007478415,0.0007077552,0.00001526743],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943403,0.0004306865,0.003200088,0.0002329385,0.0000309324,0.0000169308,0.0001910715,0.0001314948,0.001425532],"genre_scores_gemma":[0.9981799,0.0001527146,0.0006486273,0.00002982887,0.000006898253,0.000008535648,0.0001388477,0.00002271963,0.0008118686],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003040895,"threshold_uncertainty_score":0.01017284,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004851306968549459,"score_gpt":0.2674922535485484,"score_spread":0.262640946579999,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}