{"id":"W2727207649","doi":"10.1139/cjc-2017-0277","title":"Octahedral Co(III) salen complexes: the role of peripheral ligand electronics on axial ligand release upon reduction","year":2017,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Ligand (biochemistry); Octahedron; Redox; Schiff base; Imidazole; Medicinal chemistry; Quenching (fluorescence); Ring (chemistry); Crystallography; Stereochemistry; Fluorescence; Inorganic chemistry; Crystal structure; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008587478,0.0001871382,0.0001842645,0.00005674826,0.00007673157,0.0002479727,0.0002357968,0.0002146715,0.0006971781],"category_scores_gemma":[0.0001526516,0.00009468817,0.00005263897,0.00007763576,0.0002205649,0.0001185298,0.0001886952,0.000194228,0.0001625604],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002227455,"about_ca_system_score_gemma":0.00008846803,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004174172,"about_ca_topic_score_gemma":0.001227432,"domain_scores_codex":[0.9999316,0.0000128424,0.00000484471,0.00001207742,0.0000227125,0.00001586099],"domain_scores_gemma":[0.9999464,0.000009659307,0.00001500534,0.000004146286,0.00001024412,0.00001450573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002152185,0.00001233518,0.0001184919,0.00003946181,0.000003356653,0.00003361041,0.00002326611,0.0001568323,0.9978143,0.0001471102,0.00004370357,0.001392435],"study_design_scores_gemma":[0.0000137643,0.0001566371,0.0005401323,0.000002657376,0.00000778252,0.00008854968,0.00001534508,0.0007632443,0.997059,0.00002458441,0.00132423,0.000004144048],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959552,0.0003348707,0.001871553,0.00003978302,0.0000142249,0.00001980821,0.00005188565,0.00004928163,0.001663389],"genre_scores_gemma":[0.9973815,0.0001727915,0.001368016,0.00002113256,0.000002247065,0.000007464668,0.00005664284,0.00001054342,0.0009796609],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006971781,"threshold_uncertainty_score":0.00233227,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02085645277429498,"score_gpt":0.2487967930159338,"score_spread":0.2279403402416388,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}