{"id":"W2728861371","doi":"10.1021/ie400766b","title":"Reduction Kinetics of Perovskite-Based Oxygen Carriers for Chemical Looping Combustion","year":2013,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Chemical Looping and Thermochemical Processes","field":"Engineering","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemical looping combustion; Diffusion; Chemistry; Oxygen; Nucleation; Activation energy; Perovskite (structure); Analytical Chemistry (journal); Combustion; Phase (matter); Materials science; Thermodynamics; Physical chemistry; Crystallography; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001914912,0.0003341448,0.0003145231,0.000180753,0.0001188286,0.0002129952,0.0004192725,0.0002656892,0.0006508082],"category_scores_gemma":[0.0003293279,0.000143263,0.0002398588,0.0001517772,0.0001621625,0.0003139892,0.0001420025,0.000330239,0.0001809796],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004191555,"about_ca_system_score_gemma":0.0002181707,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001521157,"about_ca_topic_score_gemma":0.002146332,"domain_scores_codex":[0.9998956,0.00001011142,0.000005341384,0.00002289575,0.00004329549,0.0000227952],"domain_scores_gemma":[0.9998975,0.00003459734,0.00002493731,0.000005144446,0.00002745941,0.00001041515],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009886659,0.00001754973,0.0001928131,0.00005571645,0.000004262131,0.00002410334,0.00004147537,0.0007638918,0.9972302,0.00009550336,0.00003537179,0.001440236],"study_design_scores_gemma":[0.00000727202,0.0001530885,0.0003832825,0.000002218253,0.000005493733,0.0000149647,0.00001507193,0.007155821,0.9918469,0.00001864156,0.0003915482,0.000005574429],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983341,0.0001631629,0.001052176,0.00001707349,0.000007027878,0.000009051365,0.00005792446,0.0000488038,0.000310639],"genre_scores_gemma":[0.9976422,0.0001614078,0.001206141,0.000007026987,0.000002468029,0.00001169813,0.00009043415,0.00001884052,0.0008597547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001521157,"threshold_uncertainty_score":0.003041208,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0573998482470484,"score_gpt":0.2862650330901694,"score_spread":0.228865184843121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}