{"id":"W2729349265","doi":"10.1107/s2052252517008326","title":"Structure-directing effects of ionic liquids in the ionothermal synthesis of metal–organic frameworks","year":2017,"lang":"en","type":"review","venue":"IUCrJ","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Excellence Research Chairs, Government of Canada","keywords":"Ionic liquid; Chemistry; Metal-organic framework; Linker; Solvent; Ion; Combinatorial chemistry; Solvothermal synthesis; Ionic bonding; Metal; Organic synthesis; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006708329,0.0005723353,0.002520757,0.0001544644,0.0001598971,0.00006224743,0.001967222,0.001630238,0.001512993],"category_scores_gemma":[0.003104457,0.0003864768,0.0007938402,0.0003776197,0.0002049632,0.00006772496,0.0001833375,0.001817948,0.00002227885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008173528,"about_ca_system_score_gemma":0.0002311196,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003992958,"about_ca_topic_score_gemma":0.00001732286,"domain_scores_codex":[0.9970797,0.0002989395,0.001236117,0.0005677835,0.0004273204,0.0003901173],"domain_scores_gemma":[0.9906881,0.005042114,0.001792923,0.002351681,0.00006490786,0.00006023779],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000004193841,0.0001526584,0.000006225295,0.02360896,0.0004670513,0.000005883085,0.0002018692,0.000001379202,0.002714926,0.0008295006,0.00005446403,0.9719529],"study_design_scores_gemma":[0.0004398502,0.00006262212,0.00006160539,0.1295125,0.008837231,0.0001283694,0.0002475949,0.0000439144,0.1725723,0.002423671,0.6836601,0.002010211],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.001918173,0.9942778,0.00006236011,0.00004255291,0.0001761871,0.0005232703,0.00008684947,0.00003943962,0.00287335],"genre_scores_gemma":[0.09360313,0.9049678,0.0004549429,0.00001836395,0.0003504735,0.0002828982,0.00002096629,0.0001340827,0.0001673057],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9699427,"threshold_uncertainty_score":0.9998587,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0273523639657923,"score_gpt":0.3103137168939133,"score_spread":0.282961352928121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}