{"id":"W2732174948","doi":"10.1021/acs.organomet.7b00313","title":"Water-Soluble Phosphaviologens for Effective Photoinduced Charge Separation","year":2017,"lang":"en","type":"article","venue":"Organometallics","topic":"Advanced Photocatalysis Techniques","field":"Energy","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Photodegradation; Chemistry; Photocatalysis; Methylene blue; Anatase; Aqueous solution; Titanium dioxide; Solubility; Photochemistry; Photoinduced charge separation; Chemical engineering; Combinatorial chemistry; Organic chemistry; Catalysis; Artificial photosynthesis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001155577,0.0003706322,0.0001241149,0.000192183,0.00009764107,0.0002940754,0.0002619467,0.0002868246,0.001471063],"category_scores_gemma":[0.0002003034,0.0001707042,0.0001028452,0.0001429462,0.0001861304,0.0003296514,0.0002417914,0.0004673681,0.0003491922],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001719084,"about_ca_system_score_gemma":0.0001672199,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001570346,"about_ca_topic_score_gemma":0.0003342436,"domain_scores_codex":[0.9999117,0.00001203033,0.000007791607,0.00002107031,0.00002883592,0.00001861297],"domain_scores_gemma":[0.9999201,0.00002035661,0.00002816753,0.000007851721,0.0000105302,0.00001300487],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002777393,0.00001301312,0.00003014251,0.00005162515,0.000001953937,0.0000377671,0.00001215183,0.0001666687,0.9968144,0.0004711597,0.00003623757,0.002337088],"study_design_scores_gemma":[0.000006033261,0.00004740054,0.00006639249,0.000001499097,0.000002472284,0.00004469722,0.000004485527,0.0003220963,0.997985,0.00004948083,0.00146827,0.00000208808],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9249328,0.002751437,0.06389313,0.0002829571,0.00008039066,0.0001452152,0.0003423115,0.0003871393,0.007184667],"genre_scores_gemma":[0.9811454,0.001037788,0.01388527,0.00005343447,0.00001105995,0.00003789838,0.000150284,0.00004460897,0.00363418],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001471063,"threshold_uncertainty_score":0.004921198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02232243751129165,"score_gpt":0.318260540893372,"score_spread":0.2959381033820803,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}