{"id":"W2734448206","doi":"10.1002/ijch.201700035","title":"Iron Complexes with Chiral N/P Macrocycles as Catalysts for Asymmetric Transfer Hydrogenation","year":2017,"lang":"en","type":"article","venue":"Israel Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Toronto; Eidgenössische Technische Hochschule Zürich; Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung","keywords":"Stereocenter; Chemistry; Catalysis; Enantioselective synthesis; Transfer hydrogenation; Combinatorial chemistry; Base (topology); Asymmetric hydrogenation; Organic chemistry; Ruthenium","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001251901,0.0002819626,0.0001787009,0.0002412376,0.0001329377,0.0002785372,0.0003141279,0.0002599293,0.001357623],"category_scores_gemma":[0.0001594699,0.0001300515,0.000102402,0.0000828178,0.0002046479,0.0001794253,0.0002984406,0.0002767916,0.0005026406],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003272316,"about_ca_system_score_gemma":0.0001495355,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005000484,"about_ca_topic_score_gemma":0.00109402,"domain_scores_codex":[0.999902,0.00001808716,0.000005850104,0.00001874098,0.00002823558,0.00002710993],"domain_scores_gemma":[0.9999638,0.000005753021,0.00000814552,0.000003866505,0.000004841809,0.00001358506],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003492114,0.00009867694,0.0002423436,0.0002035893,0.00002013173,0.0004172011,0.00008138088,0.001516542,0.9715248,0.00561999,0.001522386,0.01840375],"study_design_scores_gemma":[0.00008111208,0.0005718885,0.0006234257,0.00002022277,0.00001610373,0.0001660527,0.00002159165,0.003660952,0.9766237,0.0004195743,0.01777655,0.00001880045],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.946251,0.004575653,0.01294186,0.0003665026,0.0002603971,0.0001454489,0.0002093258,0.0005050853,0.03474472],"genre_scores_gemma":[0.9923956,0.0008121883,0.002510157,0.00007554932,0.00002681967,0.0000349403,0.00008142711,0.00003598951,0.004027249],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001357623,"threshold_uncertainty_score":0.004541695,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01173625828291533,"score_gpt":0.2611150565158931,"score_spread":0.2493787982329778,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}